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A two-dimensional coordination polymer: poly[[bis[μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3) N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]
The title compound, {[Cd(C(9)H(11)N(2)S(2))(2)]·C(6)H(7)N}(n), features two μ(2)-κ(3)-dithiocarbamate ligands each of which chelates one Cd(II) atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending par...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382605/ https://www.ncbi.nlm.nih.gov/pubmed/28435704 http://dx.doi.org/10.1107/S2056989017003516 |
Sumario: | The title compound, {[Cd(C(9)H(11)N(2)S(2))(2)]·C(6)H(7)N}(n), features two μ(2)-κ(3)-dithiocarbamate ligands each of which chelates one Cd(II) atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the ab plane with square channels along the b axis. The Cd(II) atom geometry is based on a distorted cis-N(2)S(4) octahedron. The 3-methylpyridine molecules reside in the channels aligned along the b axis, being held in place by methylene-C—H⋯N(3-methylpyridine) and (3-methylpyridine)-C—H⋯π(pyridyl) interactions. Pyridyl-C—H⋯S and dithiocarbamate-methyl-C—H⋯π(pyridyl) interactions provide connections between layers along the c axis. |
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