A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]

The title compound, {[Cd(C(9)H(11)N(2)S(2))(2)]·C(6)H(7)N}(n), features two μ(2)-κ(3)-di­thio­carbamate ligands each of which chelates one Cd(II) atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending par...

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Autores principales: Arman, Hadi D., Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382605/
https://www.ncbi.nlm.nih.gov/pubmed/28435704
http://dx.doi.org/10.1107/S2056989017003516
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author Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The title compound, {[Cd(C(9)H(11)N(2)S(2))(2)]·C(6)H(7)N}(n), features two μ(2)-κ(3)-di­thio­carbamate ligands each of which chelates one Cd(II) atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the ab plane with square channels along the b axis. The Cd(II) atom geometry is based on a distorted cis-N(2)S(4) octa­hedron. The 3-methyl­pyridine mol­ecules reside in the channels aligned along the b axis, being held in place by methyl­ene-C—H⋯N(3-methyl­pyridine) and (3-methyl­pyridine)-C—H⋯π(pyrid­yl) inter­actions. Pyridyl-C—H⋯S and di­thio­carbamate-methyl-C—H⋯π(pyrid­yl) inter­actions provide connections between layers along the c axis.
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spelling pubmed-53826052017-04-21 A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate] Arman, Hadi D. Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, {[Cd(C(9)H(11)N(2)S(2))(2)]·C(6)H(7)N}(n), features two μ(2)-κ(3)-di­thio­carbamate ligands each of which chelates one Cd(II) atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the ab plane with square channels along the b axis. The Cd(II) atom geometry is based on a distorted cis-N(2)S(4) octa­hedron. The 3-methyl­pyridine mol­ecules reside in the channels aligned along the b axis, being held in place by methyl­ene-C—H⋯N(3-methyl­pyridine) and (3-methyl­pyridine)-C—H⋯π(pyrid­yl) inter­actions. Pyridyl-C—H⋯S and di­thio­carbamate-methyl-C—H⋯π(pyrid­yl) inter­actions provide connections between layers along the c axis. International Union of Crystallography 2017-03-10 /pmc/articles/PMC5382605/ /pubmed/28435704 http://dx.doi.org/10.1107/S2056989017003516 Text en © Arman et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Arman, Hadi D.
Poplaukhin, Pavel
Tiekink, Edward R. T.
A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]
title A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]
title_full A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]
title_fullStr A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]
title_full_unstemmed A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]
title_short A two-dimensional coordination polymer: poly[[bis­[μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) N:S,S′]cadmium(II)] 3-methyl­pyridine monosolvate]
title_sort two-dimensional coordination polymer: poly[[bis­[μ(2)-n-ethyl-n-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) n:s,s′]cadmium(ii)] 3-methyl­pyridine monosolvate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382605/
https://www.ncbi.nlm.nih.gov/pubmed/28435704
http://dx.doi.org/10.1107/S2056989017003516
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