Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate

The title complex, [PdCl(2)(C(8)H(14)N(2)O)(2)]·2H(2)O, was obtained by N–O bond cleavage of the oxa­diazo­line rings of the trans-[di­chlorido-bis­(2,5,5-trimethyl-5,6,7,7a-tetra­hydro­pyrrolo­[1,2-b][1,2,4]oxa­diazole-N (1))]palladium(II) complex. The palladium(II) atom exhibits an almost square-p...

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Autores principales: Lasri, Jamal, Eltayeb, Naser Eltaher, Haukka, Matti, Babgi, Bandar A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382614/
https://www.ncbi.nlm.nih.gov/pubmed/28435713
http://dx.doi.org/10.1107/S2056989017003929
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author Lasri, Jamal
Eltayeb, Naser Eltaher
Haukka, Matti
Babgi, Bandar A.
author_facet Lasri, Jamal
Eltayeb, Naser Eltaher
Haukka, Matti
Babgi, Bandar A.
author_sort Lasri, Jamal
collection PubMed
description The title complex, [PdCl(2)(C(8)H(14)N(2)O)(2)]·2H(2)O, was obtained by N–O bond cleavage of the oxa­diazo­line rings of the trans-[di­chlorido-bis­(2,5,5-trimethyl-5,6,7,7a-tetra­hydro­pyrrolo­[1,2-b][1,2,4]oxa­diazole-N (1))]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two trans-arranged chloride anions and a nitro­gen atom from each of the two neutral organic ligands. In the crystal, N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds link complex mol­ecules into double layers parallel to the bc plane.
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spelling pubmed-53826142017-04-21 Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate Lasri, Jamal Eltayeb, Naser Eltaher Haukka, Matti Babgi, Bandar A. Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [PdCl(2)(C(8)H(14)N(2)O)(2)]·2H(2)O, was obtained by N–O bond cleavage of the oxa­diazo­line rings of the trans-[di­chlorido-bis­(2,5,5-trimethyl-5,6,7,7a-tetra­hydro­pyrrolo­[1,2-b][1,2,4]oxa­diazole-N (1))]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two trans-arranged chloride anions and a nitro­gen atom from each of the two neutral organic ligands. In the crystal, N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds link complex mol­ecules into double layers parallel to the bc plane. International Union of Crystallography 2017-03-17 /pmc/articles/PMC5382614/ /pubmed/28435713 http://dx.doi.org/10.1107/S2056989017003929 Text en © Lasri et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Lasri, Jamal
Eltayeb, Naser Eltaher
Haukka, Matti
Babgi, Bandar A.
Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
title Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
title_full Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
title_fullStr Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
title_full_unstemmed Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
title_short Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
title_sort crystal structure of trans-di­chloridobis­[n-(5,5-di­methyl-4,5-di­hydro-3h-pyrrol-2-yl-κn)acetamide]palladium(ii) dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382614/
https://www.ncbi.nlm.nih.gov/pubmed/28435713
http://dx.doi.org/10.1107/S2056989017003929
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