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Crystal structure of N-(2-benzoyl-5-ethynylphen­yl)quinoline-2-carboxamide

In the title compound, C(25)H(16)N(2)O(2), the quinoline ring system is essentially planar, with a maximum deviation of 0.030 (1) Å, and forms a dihedral angle of 20.9 (1)° with benzoyl benzene ring. The unsubstituted phenyl ring forms dihedral angles of 52.7 (1)° with the quinoline ring system and...

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Detalles Bibliográficos
Autores principales: Peña-Solórzano, Diana, König, Burkhard, Sierra, Cesar A., Ochoa-Puentes, Cristian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382631/
https://www.ncbi.nlm.nih.gov/pubmed/28435730
http://dx.doi.org/10.1107/S2056989017004601
Descripción
Sumario:In the title compound, C(25)H(16)N(2)O(2), the quinoline ring system is essentially planar, with a maximum deviation of 0.030 (1) Å, and forms a dihedral angle of 20.9 (1)° with benzoyl benzene ring. The unsubstituted phenyl ring forms dihedral angles of 52.7 (1)° with the quinoline ring system and 54.1 (1)° with the ethynyl-substituted benzene ring. The mol­ecule contains an intra­molecular bifurcated N—H⋯(O,N) hydrogen bond, forming S(5) and S(6) rings, which may influence the conformation of the mol­ecule. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. In addition, the three-dimensional structure contains π–π stacking inter­actions, with centroid–centroid distances of 3.695 (1) and 3.751 (1) Å.