Crystal structure of bis­(4-benzoyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

The crystal structure of the title compound, [Co(NCS)(2)(C(12)H(9)NO)(2)(CH(3)OH)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by two N-terminal bonding thio­cyanato anions, two methanol mol­ecules and two 4-benzoyl­pyridine ligands into discrete complexes that are located...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382634/
https://www.ncbi.nlm.nih.gov/pubmed/28435733
http://dx.doi.org/10.1107/S2056989017004765
Descripción
Sumario:The crystal structure of the title compound, [Co(NCS)(2)(C(12)H(9)NO)(2)(CH(3)OH)(2)], consists of cobalt(II) cations that are octa­hedrally coordinated by two N-terminal bonding thio­cyanato anions, two methanol mol­ecules and two 4-benzoyl­pyridine ligands into discrete complexes that are located on centres of inversion. These complexes are further linked by O—H⋯O hydrogen bonding between the hy­droxy H atom of the methanol ligand and the carbonyl O atom of the 4-benzoyl­pyridine ligand of a neighboring complex into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers.

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