Cargando…

Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol

In the title compound, C(17)H(18)N(2)O, the central carbon atom with the OH substituent and one of the (E)-benzyl­idene­amino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotat...

Descripción completa

Detalles Bibliográficos
Autores principales: Rivera, Augusto, Miranda-Carvajal, Ingrid, Ríos-Motta, Jaime, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382637/
https://www.ncbi.nlm.nih.gov/pubmed/28435736
http://dx.doi.org/10.1107/S2056989017004741
_version_ 1782520140779225088
author Rivera, Augusto
Miranda-Carvajal, Ingrid
Ríos-Motta, Jaime
Bolte, Michael
author_facet Rivera, Augusto
Miranda-Carvajal, Ingrid
Ríos-Motta, Jaime
Bolte, Michael
author_sort Rivera, Augusto
collection PubMed
description In the title compound, C(17)H(18)N(2)O, the central carbon atom with the OH substituent and one of the (E)-benzyl­idene­amino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotation of approximately 60° about the C—N single bond. In the crystal, the mol­ecules are held together by O—H⋯N hydrogen bonds, forming simple C(5) chains along the b-axis direction. In addition, pairs of the chains are further aggregated by weak C—H⋯π inter­actions.
format Online
Article
Text
id pubmed-5382637
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-53826372017-04-21 Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol Rivera, Augusto Miranda-Carvajal, Ingrid Ríos-Motta, Jaime Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(17)H(18)N(2)O, the central carbon atom with the OH substituent and one of the (E)-benzyl­idene­amino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotation of approximately 60° about the C—N single bond. In the crystal, the mol­ecules are held together by O—H⋯N hydrogen bonds, forming simple C(5) chains along the b-axis direction. In addition, pairs of the chains are further aggregated by weak C—H⋯π inter­actions. International Union of Crystallography 2017-03-31 /pmc/articles/PMC5382637/ /pubmed/28435736 http://dx.doi.org/10.1107/S2056989017004741 Text en © Rivera et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Rivera, Augusto
Miranda-Carvajal, Ingrid
Ríos-Motta, Jaime
Bolte, Michael
Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol
title Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol
title_full Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol
title_fullStr Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol
title_full_unstemmed Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol
title_short Crystal structure of 1,3-bis­[(E)-benzyl­idene­amino]­propan-2-ol
title_sort crystal structure of 1,3-bis­[(e)-benzyl­idene­amino]­propan-2-ol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382637/
https://www.ncbi.nlm.nih.gov/pubmed/28435736
http://dx.doi.org/10.1107/S2056989017004741
work_keys_str_mv AT riveraaugusto crystalstructureof13bisebenzylideneaminopropan2ol
AT mirandacarvajalingrid crystalstructureof13bisebenzylideneaminopropan2ol
AT riosmottajaime crystalstructureof13bisebenzylideneaminopropan2ol
AT boltemichael crystalstructureof13bisebenzylideneaminopropan2ol