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Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol
In the title compound, C(17)H(18)N(2)O, the central carbon atom with the OH substituent and one of the (E)-benzylideneamino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotat...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382637/ https://www.ncbi.nlm.nih.gov/pubmed/28435736 http://dx.doi.org/10.1107/S2056989017004741 |
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author | Rivera, Augusto Miranda-Carvajal, Ingrid Ríos-Motta, Jaime Bolte, Michael |
author_facet | Rivera, Augusto Miranda-Carvajal, Ingrid Ríos-Motta, Jaime Bolte, Michael |
author_sort | Rivera, Augusto |
collection | PubMed |
description | In the title compound, C(17)H(18)N(2)O, the central carbon atom with the OH substituent and one of the (E)-benzylideneamino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotation of approximately 60° about the C—N single bond. In the crystal, the molecules are held together by O—H⋯N hydrogen bonds, forming simple C(5) chains along the b-axis direction. In addition, pairs of the chains are further aggregated by weak C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-5382637 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-53826372017-04-21 Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol Rivera, Augusto Miranda-Carvajal, Ingrid Ríos-Motta, Jaime Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(17)H(18)N(2)O, the central carbon atom with the OH substituent and one of the (E)-benzylideneamino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotation of approximately 60° about the C—N single bond. In the crystal, the molecules are held together by O—H⋯N hydrogen bonds, forming simple C(5) chains along the b-axis direction. In addition, pairs of the chains are further aggregated by weak C—H⋯π interactions. International Union of Crystallography 2017-03-31 /pmc/articles/PMC5382637/ /pubmed/28435736 http://dx.doi.org/10.1107/S2056989017004741 Text en © Rivera et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Rivera, Augusto Miranda-Carvajal, Ingrid Ríos-Motta, Jaime Bolte, Michael Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol |
title | Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol |
title_full | Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol |
title_fullStr | Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol |
title_full_unstemmed | Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol |
title_short | Crystal structure of 1,3-bis[(E)-benzylideneamino]propan-2-ol |
title_sort | crystal structure of 1,3-bis[(e)-benzylideneamino]propan-2-ol |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382637/ https://www.ncbi.nlm.nih.gov/pubmed/28435736 http://dx.doi.org/10.1107/S2056989017004741 |
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