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Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)

The title complex, [Ni(C(20)H(14)ClN(3)O)], with an asymmetrically chloride-appended Schiff base ligand has been synthesized and structurally characterized at 100 K. In the compound, the central nickel(II) ion has a square-planar coordination geometry with N(3)O donors of the π-conjugated tetra­dent...

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Autores principales: Kobayashi, Fumiya, Koga, Atsushi, Ohtani, Ryo, Hayami, Shinya, Nakamura, Masaaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382639/
https://www.ncbi.nlm.nih.gov/pubmed/28435738
http://dx.doi.org/10.1107/S2056989017004613
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author Kobayashi, Fumiya
Koga, Atsushi
Ohtani, Ryo
Hayami, Shinya
Nakamura, Masaaki
author_facet Kobayashi, Fumiya
Koga, Atsushi
Ohtani, Ryo
Hayami, Shinya
Nakamura, Masaaki
author_sort Kobayashi, Fumiya
collection PubMed
description The title complex, [Ni(C(20)H(14)ClN(3)O)], with an asymmetrically chloride-appended Schiff base ligand has been synthesized and structurally characterized at 100 K. In the compound, the central nickel(II) ion has a square-planar coordination geometry with N(3)O donors of the π-conjugated tetra­dentate Schiff base ligand. In the crystal, the complexes are connected into an inversion dimer via an Ni⋯Ni inter­action [3.1753 (5) Å] and a pair of π–π inter­actions [centroid–centroid distance = 3.8416 (16) Å]. The dimers are linked via a C—H⋯Cl hydrogen bond, forming a chain along the c-axis direction. The dimer chains inter­act with each other through π–π inter­actions [centroid–centroid distance = 3.8736 (16) Å], forming a layer expanding parallel to the ac plane.
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spelling pubmed-53826392017-04-21 Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II) Kobayashi, Fumiya Koga, Atsushi Ohtani, Ryo Hayami, Shinya Nakamura, Masaaki Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Ni(C(20)H(14)ClN(3)O)], with an asymmetrically chloride-appended Schiff base ligand has been synthesized and structurally characterized at 100 K. In the compound, the central nickel(II) ion has a square-planar coordination geometry with N(3)O donors of the π-conjugated tetra­dentate Schiff base ligand. In the crystal, the complexes are connected into an inversion dimer via an Ni⋯Ni inter­action [3.1753 (5) Å] and a pair of π–π inter­actions [centroid–centroid distance = 3.8416 (16) Å]. The dimers are linked via a C—H⋯Cl hydrogen bond, forming a chain along the c-axis direction. The dimer chains inter­act with each other through π–π inter­actions [centroid–centroid distance = 3.8736 (16) Å], forming a layer expanding parallel to the ac plane. International Union of Crystallography 2017-03-31 /pmc/articles/PMC5382639/ /pubmed/28435738 http://dx.doi.org/10.1107/S2056989017004613 Text en © Kobayashi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Kobayashi, Fumiya
Koga, Atsushi
Ohtani, Ryo
Hayami, Shinya
Nakamura, Masaaki
Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)
title Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)
title_full Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)
title_fullStr Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)
title_full_unstemmed Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)
title_short Crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(II)
title_sort crystal structure of [2-({2-[(2-azanidyl­benzyl­idene)amino]­benzyl­idene}amino)-4-chloro­phenol­ato]nickel(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382639/
https://www.ncbi.nlm.nih.gov/pubmed/28435738
http://dx.doi.org/10.1107/S2056989017004613
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