Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition

Chiral metal catalysts have been widely applied to asymmetric transformations. However, the electronic structure of the catalyst and how it contributes to the activation of the substrate is seldom investigated. Here, we report an empirical approach for providing insights into the catalytic activatio...

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Detalles Bibliográficos
Autores principales: Sohtome, Yoshihiro, Nakamura, Genta, Muranaka, Atsuya, Hashizume, Daisuke, Lectard, Sylvain, Tsuchimoto, Teruhisa, Uchiyama, Masanobu, Sodeoka, Mikiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5384211/
https://www.ncbi.nlm.nih.gov/pubmed/28383035
http://dx.doi.org/10.1038/ncomms14875

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5384211/
https://www.ncbi.nlm.nih.gov/pubmed/28383035
http://dx.doi.org/10.1038/ncomms14875

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