Cargando…

Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor

The YSZ–NiO ceramics for solid oxide fuel cells (SOFCs) anode have been investigated. A series of specimens were singly reduced in a hydrogenous atmosphere (Ar–5 vol% H(2) mixture) at 600 °C under the pressure of 0.15 MPa or subjected to ‘reduction in the mixture–oxidation in air’ (redox) cycling at...

Descripción completa

Detalles Bibliográficos
Autores principales: Vasyliv, Bogdan, Podhurska, Viktoriya, Ostash, Orest
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5385186/
https://www.ncbi.nlm.nih.gov/pubmed/28395483
http://dx.doi.org/10.1186/s11671-017-2038-4
_version_ 1782520555670339584
author Vasyliv, Bogdan
Podhurska, Viktoriya
Ostash, Orest
author_facet Vasyliv, Bogdan
Podhurska, Viktoriya
Ostash, Orest
author_sort Vasyliv, Bogdan
collection PubMed
description The YSZ–NiO ceramics for solid oxide fuel cells (SOFCs) anode have been investigated. A series of specimens were singly reduced in a hydrogenous atmosphere (Ar–5 vol% H(2) mixture) at 600 °C under the pressure of 0.15 MPa or subjected to ‘reduction in the mixture–oxidation in air’ (redox) cycling at 600 °C. The YSZ–Ni cermets formed in both treatment conditions were then aged in ‘water vapor in Ar–5 vol% H(2) mixture’ atmosphere at 600 °C under the pressure of 0.15 MPa. Additionally, the behaviour of the as-received material in this atmosphere was studied. It was revealed that small amount of water vapor in Ar–5 vol% H(2) mixture (water vapor pressure below 0.03 MPa) does not affect the reduction of the nickel phase in the YSZ–NiO ceramics, but causes some changes in the YSZ–Ni cermet structure. In particular, nanopore growth in tiny Ni particles takes place. At higher concentration of water vapor in the mixture (water vapor pressure above 0.03–0.05 MPa), converse changes in the kinetics of reduction occur. The best physical and mechanical properties were revealed for the material treated by redox cycling after holding at 600 °C in water depleted gas mixture. The dual effect of water vapor on nickel-zirconia anode behaviour is discussed basing on scanning electron microscopy analysis data, material electrical conductivity, and strength.
format Online
Article
Text
id pubmed-5385186
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher Springer US
record_format MEDLINE/PubMed
spelling pubmed-53851862017-04-25 Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor Vasyliv, Bogdan Podhurska, Viktoriya Ostash, Orest Nanoscale Res Lett Nano Express The YSZ–NiO ceramics for solid oxide fuel cells (SOFCs) anode have been investigated. A series of specimens were singly reduced in a hydrogenous atmosphere (Ar–5 vol% H(2) mixture) at 600 °C under the pressure of 0.15 MPa or subjected to ‘reduction in the mixture–oxidation in air’ (redox) cycling at 600 °C. The YSZ–Ni cermets formed in both treatment conditions were then aged in ‘water vapor in Ar–5 vol% H(2) mixture’ atmosphere at 600 °C under the pressure of 0.15 MPa. Additionally, the behaviour of the as-received material in this atmosphere was studied. It was revealed that small amount of water vapor in Ar–5 vol% H(2) mixture (water vapor pressure below 0.03 MPa) does not affect the reduction of the nickel phase in the YSZ–NiO ceramics, but causes some changes in the YSZ–Ni cermet structure. In particular, nanopore growth in tiny Ni particles takes place. At higher concentration of water vapor in the mixture (water vapor pressure above 0.03–0.05 MPa), converse changes in the kinetics of reduction occur. The best physical and mechanical properties were revealed for the material treated by redox cycling after holding at 600 °C in water depleted gas mixture. The dual effect of water vapor on nickel-zirconia anode behaviour is discussed basing on scanning electron microscopy analysis data, material electrical conductivity, and strength. Springer US 2017-04-08 /pmc/articles/PMC5385186/ /pubmed/28395483 http://dx.doi.org/10.1186/s11671-017-2038-4 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Vasyliv, Bogdan
Podhurska, Viktoriya
Ostash, Orest
Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor
title Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor
title_full Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor
title_fullStr Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor
title_full_unstemmed Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor
title_short Preconditioning of the YSZ-NiO Fuel Cell Anode in Hydrogenous Atmospheres Containing Water Vapor
title_sort preconditioning of the ysz-nio fuel cell anode in hydrogenous atmospheres containing water vapor
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5385186/
https://www.ncbi.nlm.nih.gov/pubmed/28395483
http://dx.doi.org/10.1186/s11671-017-2038-4
work_keys_str_mv AT vasylivbogdan preconditioningoftheyszniofuelcellanodeinhydrogenousatmospherescontainingwatervapor
AT podhurskaviktoriya preconditioningoftheyszniofuelcellanodeinhydrogenousatmospherescontainingwatervapor
AT ostashorest preconditioningoftheyszniofuelcellanodeinhydrogenousatmospherescontainingwatervapor