Prediction of intrinsic two-dimensional ferroelectrics in In(2)Se(3) and other III(2)-VI(3) van der Waals materials

Interest in two-dimensional (2D) van der Waals materials has grown rapidly across multiple scientific and engineering disciplines in recent years. However, ferroelectricity, the presence of a spontaneous electric polarization, which is important in many practical applications, has rarely been reported in such materials so far. Here we employ first-principles calculations to discover a branch of the 2D materials family, based on In(2)Se(3) and other III(2)-VI(3) van der Waals materials, that exhibits room-temperature ferroelectricity with reversible spontaneous electric polarization in both out-of-plane and in-plane orientations. The device potential of these 2D ferroelectric materials is further demonstrated using the examples of van der Waals heterostructures of In(2)Se(3)/graphene, exhibiting a tunable Schottky barrier, and In(2)Se(3)/WSe(2), showing a significant band gap reduction in the combined system. These findings promise to substantially broaden the tunability of van der Waals heterostructures for a wide range of applications.