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Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles

[Image: see text] We report a highly enantioselective CuH-catalyzed Markovnikov hydrosilylation of vinylarenes and vinyl heterocycles. This method has a broad scope and enables both the synthesis of isolable silanes and the conversion of crude products to chiral alcohols. Density functional theory c...

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Detalles Bibliográficos
Autores principales:	Gribble, Michael W., Pirnot, Michael T., Bandar, Jeffrey S., Liu, Richard Y., Buchwald, Stephen L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5386394/ https://www.ncbi.nlm.nih.gov/pubmed/28117996 http://dx.doi.org/10.1021/jacs.6b13029

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