Gas chemical adsorption characterization of lanthanide hexafluoroacetylacetonates

Newly-established adsorption enthalpy and entropy values of 12 lanthanide hexafluoroacetylacetonates, denoted Ln[hfac](4), along with the experimental and theoretical methodology used to obtain these values, are presented for the first time. The results of this work can be used in conjunction with t...

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Detalles Bibliográficos
Autores principales: Stratz, S. Adam, Jones, Steven J., Mullen, Austin D., Mathuthu, Manny, Oldham, Colton J., Auxier, John D., Hall, Howard L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Netherlands 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5387005/
https://www.ncbi.nlm.nih.gov/pubmed/28458412
http://dx.doi.org/10.1007/s10967-017-5232-z
Descripción
Sumario:Newly-established adsorption enthalpy and entropy values of 12 lanthanide hexafluoroacetylacetonates, denoted Ln[hfac](4), along with the experimental and theoretical methodology used to obtain these values, are presented for the first time. The results of this work can be used in conjunction with theoretical modeling techniques to optimize a large-scale gas-phase separation experiment using isothermal chromatography. The results to date indicate average adsorption enthalpy and entropy values of the 12 Ln[hfac](4) complexes ranging from −33 to −139 kJ/mol K and −299 to −557 J/mol, respectively.

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