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Enantioselective Synthesis of (−)-Acetylapoaranotin
[Image: see text] The first enantioselective total synthesis of the epipolythiodiketopiperazine (ETP) natural product (−)-acetylapoaranotin (3) is reported. The concise synthesis was enabled by an eight-step synthesis of a key cyclohexadienol-containing amino ester building block. The absolute stere...
Autores principales: | Wang, Haoxuan, Regan, Clinton J., Codelli, Julian A., Romanato, Paola, Puchlopek-Dermenci, Angela L. A., Reisman, Sarah E. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2017
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5387676/ https://www.ncbi.nlm.nih.gov/pubmed/28349698 http://dx.doi.org/10.1021/acs.orglett.7b00418 |
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