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Formation of Gold(III) Alkyls from Gold Alkoxide Complexes

[Image: see text] The gold(III) methoxide complex (C(∧)N(∧)C)AuOMe (1) reacts with tris(p-tolyl)phosphine in benzene at room temperature under O abstraction to give the methylgold product (C(∧)N(∧)C)AuMe (2) together with O=P(p-tol)(3) ((C(∧)N(∧)C) = [2,6-(C(6)H(3)(t)Bu-4)(2)pyridine](2–)). Calculat...

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Detalles Bibliográficos
Autores principales:	Chambrier, Isabelle, Roşca, Dragoş-Adrian, Fernandez-Cestau, Julio, Hughes, David L., Budzelaar, Peter H. M., Bochmann, Manfred
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5388904/ https://www.ncbi.nlm.nih.gov/pubmed/28413238 http://dx.doi.org/10.1021/acs.organomet.7b00077

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