Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces

Aniline-terminated self-assembled monolayers (SAMs) on gold surfaces have successfully reacted with ArSO(2)NHOSO(2)Ar (Ar = 4-MeC(6)H(4) or 4-FC(6)H(4)) resulting in monolayers with sulfamide moieties and different end groups. Moreover, the sulfamide groups on the SAMs can be hydrolyzed showing the...

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Autores principales: Pantaine, Loïc, Humblot, Vincent, Coeffard, Vincent, Vallée, Anne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5389194/
https://www.ncbi.nlm.nih.gov/pubmed/28487759
http://dx.doi.org/10.3762/bjoc.13.64
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author Pantaine, Loïc
Humblot, Vincent
Coeffard, Vincent
Vallée, Anne
author_facet Pantaine, Loïc
Humblot, Vincent
Coeffard, Vincent
Vallée, Anne
author_sort Pantaine, Loïc
collection PubMed
description Aniline-terminated self-assembled monolayers (SAMs) on gold surfaces have successfully reacted with ArSO(2)NHOSO(2)Ar (Ar = 4-MeC(6)H(4) or 4-FC(6)H(4)) resulting in monolayers with sulfamide moieties and different end groups. Moreover, the sulfamide groups on the SAMs can be hydrolyzed showing the partial regeneration of the aniline surface. SAMs were characterized by water contact angle (WCA) measurements, Fourier-transform infrared reflection absorption spectroscopy (IRRAS) and X-ray photoelectron spectroscopy (XPS).
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spelling pubmed-53891942017-05-09 Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces Pantaine, Loïc Humblot, Vincent Coeffard, Vincent Vallée, Anne Beilstein J Org Chem Full Research Paper Aniline-terminated self-assembled monolayers (SAMs) on gold surfaces have successfully reacted with ArSO(2)NHOSO(2)Ar (Ar = 4-MeC(6)H(4) or 4-FC(6)H(4)) resulting in monolayers with sulfamide moieties and different end groups. Moreover, the sulfamide groups on the SAMs can be hydrolyzed showing the partial regeneration of the aniline surface. SAMs were characterized by water contact angle (WCA) measurements, Fourier-transform infrared reflection absorption spectroscopy (IRRAS) and X-ray photoelectron spectroscopy (XPS). Beilstein-Institut 2017-04-04 /pmc/articles/PMC5389194/ /pubmed/28487759 http://dx.doi.org/10.3762/bjoc.13.64 Text en Copyright © 2017, Pantaine et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Pantaine, Loïc
Humblot, Vincent
Coeffard, Vincent
Vallée, Anne
Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
title Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
title_full Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
title_fullStr Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
title_full_unstemmed Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
title_short Sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
title_sort sulfamide chemistry applied to the functionalization of self-assembled monolayers on gold surfaces
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5389194/
https://www.ncbi.nlm.nih.gov/pubmed/28487759
http://dx.doi.org/10.3762/bjoc.13.64
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