Multiple competing pathways for chemical reaction: drastic reaction shortcut for the self-catalytic double-helix formation of helicene oligomers

Competition among multiple pathways in a chemical reaction exhibits notable kinetic phenomena, particularly when amplification by self-catalysis is involved. A pseudoenantiomeric 1 : 1 mixture of an aminomethylene helicene (P)-tetramer and an (M)-pentamer formed enantiomeric hetero-double helices B...

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Detalles Bibliográficos
Autores principales: Kushida, Yo, Saito, Nozomi, Shigeno, Masanori, Yamaguchi, Masahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390785/
https://www.ncbi.nlm.nih.gov/pubmed/28451281
http://dx.doi.org/10.1039/c6sc01893a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390785/
https://www.ncbi.nlm.nih.gov/pubmed/28451281
http://dx.doi.org/10.1039/c6sc01893a

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