Cargando…

Synthesis of C (2)‐Symmetric Diphosphormonoamidites and Their Use as Ligands in Rh‐Catalyzed Hydroformylation: Relationships between Activity and Hydrolysis Stability

A series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2‐diamine unit in the backbone. New compounds were tested alongside related N‐acyl phosphoramidites as ligands in the Rh‐catalyzed hydroformylation of n‐octenes to investigate their influence on t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Morales Torres, Galina, Behrens, Stephan, Michalik, Dirk, Selent, Detlef, Spannenberg, Anke, Lühr, Susan, Dyballa, Katrin Marie, Franke, Robert, Börner, Armin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390800/ https://www.ncbi.nlm.nih.gov/pubmed/28413760 http://dx.doi.org/10.1002/open.201600152

Ejemplares similares

Dicarbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4,5,5-tetraphenyl-1,3,2-dioxaphospholan-2-yl)oxy-κP]biphenyl}hydridorhodium(I) diethyl ether monosolvate
por: Selent, Detlef, et al.
Publicado: (2012)

{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC (1)}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate
por: Selent, Detlef, et al.
Publicado: (2012)

Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4,5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ(2) P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate
por: Selent, Detlef, et al.
Publicado: (2012)

Rh-Catalyzed Hydroformylation-Initiated Bicyclization: Construction of Azabicyclic Systems
por: Chiou, Wen-Hua, et al.
Publicado: (2020)

Copper-catalyzed hydroformylation and hydroxymethylation of styrenes
por: Geng, Hui-Qing, et al.
Publicado: (2021)

Rh-catalyzed highly regioselective hydroformylation to linear aldehydes by employing porous organic polymer as a ligand
por: Wang, Zhaozhan, et al.
Publicado: (2020)

Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
por: You, Cai, et al.
Publicado: (2018)

Iridium‐Catalyzed Domino Hydroformylation/Hydrogenation of Olefins to Alcohols: Synergy of Two Ligands
por: Huang, Weiheng, et al.
Publicado: (2022)

Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins
por: Gao, Peng, et al.
Publicado: (2021)

Enhancing the stability of the Rh/ZnO catalyst by the growth of ZIF-8 for the hydroformylation of higher olefins
por: Chen, Lele, et al.
Publicado: (2020)

A substrate descriptor based approach for the prediction and understanding of the regioselectivity in caged catalyzed hydroformylation
por: Linnebank, Pim R., et al.
Publicado: (2023)

Carbonylbis{6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]-dioxaphosphepine)}hydridorhodium(I) toluene-d (8) 2.25-solvate
por: Leidecker, Benedict N., et al.
Publicado: (2023)

Low-temperature hydroformylation of ethylene by phosphorous stabilized Rh sites in a one-pot synthesized Rh-(O)-P-MFI zeolite
por: Zhao, Minjie, et al.
Publicado: (2023)

Effector responsive hydroformylation catalysis
por: Bai, Shao-Tao, et al.
Publicado: (2019)

Synthesis and Characterization of Rh/B–TNTs as a Recyclable Catalyst for Hydroformylation of Olefin Containing –CN Functional Group
por: Su, Penghe, et al.
Publicado: (2018)

Hydroformylation of vinyl acetate and cyclohexene over TiO(2) nanotube supported Rh and Ru nanoparticle catalysts
por: Chuai, Hongyuan, et al.
Publicado: (2018)

Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction
por: Jurado, Lole, et al.
Publicado: (2023)

Reductive Hydroformylation of Isosorbide Diallyl Ether
por: Ternel, Jérémy, et al.
Publicado: (2021)

Single-atom catalysts for hydroformylation of olefins
por: Tao, Shu, et al.
Publicado: (2023)

Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst
por: Wang, Liangbing, et al.
Publicado: (2016)

Synthesis of Nixantphos Core-Functionalized Amphiphilic Nanoreactors and Application to Rhodium-Catalyzed Aqueous Biphasic 1-Octene Hydroformylation
por: Joumaa, Ahmad, et al.
Publicado: (2020)

Distal-Selective Hydroformylation using Scaffolding Catalysis
por: Joe, Candice L., et al.
Publicado: (2014)

Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis
por: Nurttila, Sandra S., et al.
Publicado: (2018)

Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst
por: Jongkind, Lukas J., et al.
Publicado: (2019)

Atroposelective Ir-Catalyzed C–H Borylation of Phthalazine Heterobiaryls
por: Stehrer, Paul, et al.
Publicado: (2023)

Homogeneous hydroformylation of long chain alkenes catalyzed by water soluble phosphine rhodium complex in CH(3)OH and efficient catalyst cycling
por: Liu, Yan-li, et al.
Publicado: (2019)

Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
por: Bauer, Gerald, et al.
Publicado: (2020)

Mining hydroformylation in complex reaction network via graph theory
por: Takahashi, Keisuke, et al.
Publicado: (2021)

Efficient Palladium-Catalyzed Synthesis of 2-Aryl Propionic Acids
por: Neumann, Helfried, et al.
Publicado: (2020)

Synthesis of (–)-Indolizidine 167B based on domino hydroformylation/cyclization reactions
por: Guazzelli, Giuditta, et al.
Publicado: (2008)

A Selective and General Cobalt‐Catalyzed Hydroaminomethylation of Olefins to Amines
por: Yang, Ji, et al.
Publicado: (2021)

Cobalt‐Catalyzed Aqueous Dehydrogenation of Formic Acid
por: Zhou, Wei, et al.
Publicado: (2019)

DNA-catalyzed sequence-specific hydrolysis of DNA
por: Chandra, Madhavaiah, et al.
Publicado: (2009)

Symmetry breaking by enzyme-catalyzed epoxide hydrolysis
por: Schofield, Christopher J.
Publicado: (2018)

Rh(II)‐Catalyzed De‐symmetrization of Ethane‐1,2‐dithiol and Propane‐1,3‐dithiol Yields Metallo‐β‐lactamase Inhibitors
por: Krasavin, Mikhail, et al.
Publicado: (2021)

Size‐Selective Hydroformylation by a Rhodium Catalyst Confined in a Supramolecular Cage
por: Nurttila, Sandra S., et al.
Publicado: (2018)

Asymmetric Hydroformylation Using a Rhodium Catalyst Encapsulated in a Chiral Capsule
por: Jongkind, Lukas J., et al.
Publicado: (2020)

The mechanism of NDM-1-catalyzed carbapenem hydrolysis is distinct from that of penicillin or cephalosporin hydrolysis
por: Feng, Han, et al.
Publicado: (2017)

Palladium-Catalyzed Domino Aminocarbonylation of Alkynols: Direct and Selective Synthesis of Itaconimides
por: Ge, Yao, et al.
Publicado: (2021)

Rh-catalyzed alkoxycarbonylation of unactivated alkyl chlorides
por: Wang, Peng, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_aubkiciotqi9a5571j8moarl7u