Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes

[5]Pseudorotaxanes can be obtained by self‐sorting using heteroditopic guests and various cucurbituril homologues as hosts. The assembly and chemically induced disassembly of the pseudorotaxanes can be monitored by measuring the fluorescence of the anthracene guest in solution. Mass spectral evidenc...

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Autores principales: Carvalho, Cátia Parente, Domínguez, Zoe, Domínguez, Cristina, El‐Sheshtawy, Hamdy S., Silva, José Paulo Da, Arteaga, Jesús F., Pischel, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390802/
https://www.ncbi.nlm.nih.gov/pubmed/28413766
http://dx.doi.org/10.1002/open.201600173
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author Carvalho, Cátia Parente
Domínguez, Zoe
Domínguez, Cristina
El‐Sheshtawy, Hamdy S.
Silva, José Paulo Da
Arteaga, Jesús F.
Pischel, Uwe
author_facet Carvalho, Cátia Parente
Domínguez, Zoe
Domínguez, Cristina
El‐Sheshtawy, Hamdy S.
Silva, José Paulo Da
Arteaga, Jesús F.
Pischel, Uwe
author_sort Carvalho, Cátia Parente
collection PubMed
description [5]Pseudorotaxanes can be obtained by self‐sorting using heteroditopic guests and various cucurbituril homologues as hosts. The assembly and chemically induced disassembly of the pseudorotaxanes can be monitored by measuring the fluorescence of the anthracene guest in solution. Mass spectral evidence for the supramolecular assemblies is obtained in the gas phase. The disassembly in the gas phase can be achieved by collision‐induced dissociation leading to the corresponding [2]‐ and [3]pseudorotaxanes.
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spelling pubmed-53908022017-04-14 Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes Carvalho, Cátia Parente Domínguez, Zoe Domínguez, Cristina El‐Sheshtawy, Hamdy S. Silva, José Paulo Da Arteaga, Jesús F. Pischel, Uwe ChemistryOpen Full Papers [5]Pseudorotaxanes can be obtained by self‐sorting using heteroditopic guests and various cucurbituril homologues as hosts. The assembly and chemically induced disassembly of the pseudorotaxanes can be monitored by measuring the fluorescence of the anthracene guest in solution. Mass spectral evidence for the supramolecular assemblies is obtained in the gas phase. The disassembly in the gas phase can be achieved by collision‐induced dissociation leading to the corresponding [2]‐ and [3]pseudorotaxanes. John Wiley and Sons Inc. 2017-03-10 /pmc/articles/PMC5390802/ /pubmed/28413766 http://dx.doi.org/10.1002/open.201600173 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Carvalho, Cátia Parente
Domínguez, Zoe
Domínguez, Cristina
El‐Sheshtawy, Hamdy S.
Silva, José Paulo Da
Arteaga, Jesús F.
Pischel, Uwe
Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes
title Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes
title_full Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes
title_fullStr Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes
title_full_unstemmed Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes
title_short Five‐Component Self‐Assembly of Cucurbituril‐Based Hetero‐pseudorotaxanes
title_sort five‐component self‐assembly of cucurbituril‐based hetero‐pseudorotaxanes
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390802/
https://www.ncbi.nlm.nih.gov/pubmed/28413766
http://dx.doi.org/10.1002/open.201600173
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