One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction

A one‐pot protocol, effecting 14‐fold bromination with elemental bromine, has afforded copper β‐octabromo‐meso‐tris(2,6‐dibromo‐3,5‐dimethoxyphenyl)corrole, a new bis‐pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, wh...

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Autores principales: Norheim, Hans‐Kristian, Schneider, Christian, Gagnon, Kevin J., Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390803/
https://www.ncbi.nlm.nih.gov/pubmed/28413755
http://dx.doi.org/10.1002/open.201600168
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author Norheim, Hans‐Kristian
Schneider, Christian
Gagnon, Kevin J.
Ghosh, Abhik
author_facet Norheim, Hans‐Kristian
Schneider, Christian
Gagnon, Kevin J.
Ghosh, Abhik
author_sort Norheim, Hans‐Kristian
collection PubMed
description A one‐pot protocol, effecting 14‐fold bromination with elemental bromine, has afforded copper β‐octabromo‐meso‐tris(2,6‐dibromo‐3,5‐dimethoxyphenyl)corrole, a new bis‐pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to Mn(III) and Au(III). A single‐crystal X‐ray structure was obtained for the Mn(III) complex.
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spelling pubmed-53908032017-04-14 One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction Norheim, Hans‐Kristian Schneider, Christian Gagnon, Kevin J. Ghosh, Abhik ChemistryOpen Communications A one‐pot protocol, effecting 14‐fold bromination with elemental bromine, has afforded copper β‐octabromo‐meso‐tris(2,6‐dibromo‐3,5‐dimethoxyphenyl)corrole, a new bis‐pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to Mn(III) and Au(III). A single‐crystal X‐ray structure was obtained for the Mn(III) complex. John Wiley and Sons Inc. 2017-02-14 /pmc/articles/PMC5390803/ /pubmed/28413755 http://dx.doi.org/10.1002/open.201600168 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Norheim, Hans‐Kristian
Schneider, Christian
Gagnon, Kevin J.
Ghosh, Abhik
One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
title One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
title_full One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
title_fullStr One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
title_full_unstemmed One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
title_short One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction
title_sort one‐pot synthesis of a bis‐pocket corrole through a 14‐fold bromination reaction
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390803/
https://www.ncbi.nlm.nih.gov/pubmed/28413755
http://dx.doi.org/10.1002/open.201600168
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