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One‐Pot Synthesis of a bis‐Pocket Corrole through a 14‐fold Bromination Reaction

A one‐pot protocol, effecting 14‐fold bromination with elemental bromine, has afforded copper β‐octabromo‐meso‐tris(2,6‐dibromo‐3,5‐dimethoxyphenyl)corrole, a new bis‐pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, wh...

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Detalles Bibliográficos
Autores principales:	Norheim, Hans‐Kristian, Schneider, Christian, Gagnon, Kevin J., Ghosh, Abhik
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5390803/ https://www.ncbi.nlm.nih.gov/pubmed/28413755 http://dx.doi.org/10.1002/open.201600168

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