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N‐Methyl‐Benzothiazolium Salts as Carbon Lewis Acids for Si−H σ‐Bond Activation and Catalytic (De)hydrosilylation
N−Me‐Benzothiazolium salts are introduced as a new family of Lewis acids able to activate Si−H σ bonds. These carbon‐centred Lewis acids were demonstrated to have comparable Lewis acidity towards hydride as found for the triarylboranes widely used in Si−H σ‐bond activation. However, they display low...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396135/ https://www.ncbi.nlm.nih.gov/pubmed/27780294 http://dx.doi.org/10.1002/chem.201604613 |