HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid

We describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phas...

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Detalles Bibliográficos
Autores principales: Hinz, Alexander, Labbow, René, Rennick, Chris, Schulz, Axel, Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396272/
https://www.ncbi.nlm.nih.gov/pubmed/28252258
http://dx.doi.org/10.1002/anie.201700368
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author Hinz, Alexander
Labbow, René
Rennick, Chris
Schulz, Axel
Goicoechea, Jose M.
author_facet Hinz, Alexander
Labbow, René
Rennick, Chris
Schulz, Axel
Goicoechea, Jose M.
author_sort Hinz, Alexander
collection PubMed
description We describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution.
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spelling pubmed-53962722017-04-25 HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid Hinz, Alexander Labbow, René Rennick, Chris Schulz, Axel Goicoechea, Jose M. Angew Chem Int Ed Engl Communications We describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution. John Wiley and Sons Inc. 2017-03-02 2017-03-27 /pmc/articles/PMC5396272/ /pubmed/28252258 http://dx.doi.org/10.1002/anie.201700368 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Hinz, Alexander
Labbow, René
Rennick, Chris
Schulz, Axel
Goicoechea, Jose M.
HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid
title HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid
title_full HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid
title_fullStr HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid
title_full_unstemmed HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid
title_short HPCO—A Phosphorus‐Containing Analogue of Isocyanic Acid
title_sort hpco—a phosphorus‐containing analogue of isocyanic acid
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396272/
https://www.ncbi.nlm.nih.gov/pubmed/28252258
http://dx.doi.org/10.1002/anie.201700368
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