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Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations

Lower Lewis acidity boranes demonstrate greater tolerance to combinations of water/strong Brønsted bases than B(C(6)F(5))(3), this enables Si−H bond activation by a frustrated Lewis pair (FLP) mechanism to proceed in the presence of H(2)O/alkylamines. Specifically, BPh(3) has improved water toleranc...

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Detalles Bibliográficos
Autores principales:	Fasano, Valerio, Ingleson, Michael J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396349/ https://www.ncbi.nlm.nih.gov/pubmed/27977048 http://dx.doi.org/10.1002/chem.201605466

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