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A Vesicle‐to‐Worm Transition Provides a New High‐Temperature Oil Thickening Mechanism

Diblock copolymer vesicles are prepared via RAFT dispersion polymerization directly in mineral oil. Such vesicles undergo a vesicle‐to‐worm transition on heating to 150 °C, as judged by TEM and SAXS. Variable‐temperature (1)H NMR spectroscopy indicates that this transition is the result of surface p...

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Detalles Bibliográficos
Autores principales: Derry, Matthew J., Mykhaylyk, Oleksandr O., Armes, Steven P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5396375/
https://www.ncbi.nlm.nih.gov/pubmed/28071844
http://dx.doi.org/10.1002/anie.201609365