Enhanced superconductivity accompanying a Lifshitz transition in electron-doped FeSe monolayer

The origin of enhanced superconductivity over 50 K in the recently discovered FeSe monolayer films grown on SrTiO(3) (STO), as compared to 8 K in bulk FeSe, is intensely debated. As with the ferrochalcogenides A(x)Fe(2−y)Se(2) and potassium-doped FeSe, which also have a relatively high-superconducting critical temperature (T(c)), the Fermi surface (FS) of the FeSe/STO monolayer films is free of hole-like FS, suggesting that a Lifshitz transition by which these hole FSs vanish may help increasing T(c). However, the fundamental reasons explaining this increase of T(c) remain unclear. Here we report a 15 K jump of T(c) accompanying a second Lifshitz transition characterized by the emergence of an electron pocket at the Brillouin zone centre, which is triggered by high-electron doping following in situ deposition of potassium on FeSe/STO monolayer films. Our results suggest that the pairing interactions are orbital dependent in generating enhanced superconductivity in FeSe.