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Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System

Formation and electronic excitation energy transfer process in the nanosystem consisting of Ce(0.85)Tb(0.15)F(3) nanoparticles, cetrimonium bromide (CTAB) surfactant, and chlorin e(6) photosensitizer were studied. It was shown that chlorin e(6) molecules bind to Ce(0.85)Tb(0.15)F(3) NP in the presen...

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Autores principales: Losytskyy, Mykhaylo Yu., Kuzmenko, Liliia V., Shcherbakov, Oleksandr B., Gamaleia, Nikolai F., Marynin, Andrii I., Yashchuk, Valeriy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5403780/
https://www.ncbi.nlm.nih.gov/pubmed/28445996
http://dx.doi.org/10.1186/s11671-017-2077-x
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author Losytskyy, Mykhaylo Yu.
Kuzmenko, Liliia V.
Shcherbakov, Oleksandr B.
Gamaleia, Nikolai F.
Marynin, Andrii I.
Yashchuk, Valeriy M.
author_facet Losytskyy, Mykhaylo Yu.
Kuzmenko, Liliia V.
Shcherbakov, Oleksandr B.
Gamaleia, Nikolai F.
Marynin, Andrii I.
Yashchuk, Valeriy M.
author_sort Losytskyy, Mykhaylo Yu.
collection PubMed
description Formation and electronic excitation energy transfer process in the nanosystem consisting of Ce(0.85)Tb(0.15)F(3) nanoparticles, cetrimonium bromide (CTAB) surfactant, and chlorin e(6) photosensitizer were studied. It was shown that chlorin e(6) molecules bind to Ce(0.85)Tb(0.15)F(3) NP in the presence of CTAB forming thus Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem. We consider that binding occurs via chlorin e(6) embedding in the shell of CTAB molecules, formed around NP. In the Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem, electronic excitation energy transfer from Ce(3+) to chlorin e(6) takes place both directly (with the 0.33 efficiency for 2 μM chlorin e(6)) and via Tb(3+).
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spelling pubmed-54037802017-05-11 Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System Losytskyy, Mykhaylo Yu. Kuzmenko, Liliia V. Shcherbakov, Oleksandr B. Gamaleia, Nikolai F. Marynin, Andrii I. Yashchuk, Valeriy M. Nanoscale Res Lett Nano Express Formation and electronic excitation energy transfer process in the nanosystem consisting of Ce(0.85)Tb(0.15)F(3) nanoparticles, cetrimonium bromide (CTAB) surfactant, and chlorin e(6) photosensitizer were studied. It was shown that chlorin e(6) molecules bind to Ce(0.85)Tb(0.15)F(3) NP in the presence of CTAB forming thus Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem. We consider that binding occurs via chlorin e(6) embedding in the shell of CTAB molecules, formed around NP. In the Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem, electronic excitation energy transfer from Ce(3+) to chlorin e(6) takes place both directly (with the 0.33 efficiency for 2 μM chlorin e(6)) and via Tb(3+). Springer US 2017-04-24 /pmc/articles/PMC5403780/ /pubmed/28445996 http://dx.doi.org/10.1186/s11671-017-2077-x Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Losytskyy, Mykhaylo Yu.
Kuzmenko, Liliia V.
Shcherbakov, Oleksandr B.
Gamaleia, Nikolai F.
Marynin, Andrii I.
Yashchuk, Valeriy M.
Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
title Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
title_full Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
title_fullStr Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
title_full_unstemmed Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
title_short Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
title_sort energy transfer in ce(0.85)tb(0.15)f(3) nanoparticles-ctab shell-chlorin e(6) system
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5403780/
https://www.ncbi.nlm.nih.gov/pubmed/28445996
http://dx.doi.org/10.1186/s11671-017-2077-x
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