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Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System
Formation and electronic excitation energy transfer process in the nanosystem consisting of Ce(0.85)Tb(0.15)F(3) nanoparticles, cetrimonium bromide (CTAB) surfactant, and chlorin e(6) photosensitizer were studied. It was shown that chlorin e(6) molecules bind to Ce(0.85)Tb(0.15)F(3) NP in the presen...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer US
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5403780/ https://www.ncbi.nlm.nih.gov/pubmed/28445996 http://dx.doi.org/10.1186/s11671-017-2077-x |
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author | Losytskyy, Mykhaylo Yu. Kuzmenko, Liliia V. Shcherbakov, Oleksandr B. Gamaleia, Nikolai F. Marynin, Andrii I. Yashchuk, Valeriy M. |
author_facet | Losytskyy, Mykhaylo Yu. Kuzmenko, Liliia V. Shcherbakov, Oleksandr B. Gamaleia, Nikolai F. Marynin, Andrii I. Yashchuk, Valeriy M. |
author_sort | Losytskyy, Mykhaylo Yu. |
collection | PubMed |
description | Formation and electronic excitation energy transfer process in the nanosystem consisting of Ce(0.85)Tb(0.15)F(3) nanoparticles, cetrimonium bromide (CTAB) surfactant, and chlorin e(6) photosensitizer were studied. It was shown that chlorin e(6) molecules bind to Ce(0.85)Tb(0.15)F(3) NP in the presence of CTAB forming thus Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem. We consider that binding occurs via chlorin e(6) embedding in the shell of CTAB molecules, formed around NP. In the Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem, electronic excitation energy transfer from Ce(3+) to chlorin e(6) takes place both directly (with the 0.33 efficiency for 2 μM chlorin e(6)) and via Tb(3+). |
format | Online Article Text |
id | pubmed-5403780 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | Springer US |
record_format | MEDLINE/PubMed |
spelling | pubmed-54037802017-05-11 Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System Losytskyy, Mykhaylo Yu. Kuzmenko, Liliia V. Shcherbakov, Oleksandr B. Gamaleia, Nikolai F. Marynin, Andrii I. Yashchuk, Valeriy M. Nanoscale Res Lett Nano Express Formation and electronic excitation energy transfer process in the nanosystem consisting of Ce(0.85)Tb(0.15)F(3) nanoparticles, cetrimonium bromide (CTAB) surfactant, and chlorin e(6) photosensitizer were studied. It was shown that chlorin e(6) molecules bind to Ce(0.85)Tb(0.15)F(3) NP in the presence of CTAB forming thus Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem. We consider that binding occurs via chlorin e(6) embedding in the shell of CTAB molecules, formed around NP. In the Ce(0.85)Tb(0.15)F(3) NP-CTAB-chlorin e(6) nanosystem, electronic excitation energy transfer from Ce(3+) to chlorin e(6) takes place both directly (with the 0.33 efficiency for 2 μM chlorin e(6)) and via Tb(3+). Springer US 2017-04-24 /pmc/articles/PMC5403780/ /pubmed/28445996 http://dx.doi.org/10.1186/s11671-017-2077-x Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
spellingShingle | Nano Express Losytskyy, Mykhaylo Yu. Kuzmenko, Liliia V. Shcherbakov, Oleksandr B. Gamaleia, Nikolai F. Marynin, Andrii I. Yashchuk, Valeriy M. Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System |
title | Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System |
title_full | Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System |
title_fullStr | Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System |
title_full_unstemmed | Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System |
title_short | Energy Transfer in Ce(0.85)Tb(0.15)F(3) Nanoparticles-CTAB Shell-Chlorin e(6) System |
title_sort | energy transfer in ce(0.85)tb(0.15)f(3) nanoparticles-ctab shell-chlorin e(6) system |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5403780/ https://www.ncbi.nlm.nih.gov/pubmed/28445996 http://dx.doi.org/10.1186/s11671-017-2077-x |
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