Cargando…
Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes
[Image: see text] Enzymes catalyze organic transformations with exquisite levels of selectivity, including chemoselectivity, stereoselectivity, and substrate selectivity, but the types of reactions catalyzed by enzymes are more limited than those of chemical catalysts. Thus, the convergence of chemi...
Autores principales: | Key, Hanna M., Dydio, Paweł, Liu, Zhennan, Rha, Jennifer Y.-E., Nazarenko, Andrew, Seyedkazemi, Vida, Clark, Douglas S., Hartwig, John F. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2017
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5408332/ https://www.ncbi.nlm.nih.gov/pubmed/28470047 http://dx.doi.org/10.1021/acscentsci.6b00391 |
Ejemplares similares
-
Enantioselective
Intramolecular Iridium-Catalyzed
Cyclopropanation of α-Carbonyl Sulfoxonium Ylides
por: Vidal, Lucas, et al.
Publicado: (2022) -
Diverse Engineered Heme Proteins Enable Stereodivergent
Cyclopropanation of Unactivated Alkenes
por: Knight, Anders M., et al.
Publicado: (2018) -
Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes
por: Xu, Xue, et al.
Publicado: (2017) -
A Vinyl Cyclopropane Ring Expansion and Iridium‐Catalyzed Hydrogen Borrowing Cascade
por: Wübbolt, Simon, et al.
Publicado: (2020) -
Combined Experimental and Computational Study of Ruthenium N-Hydroxyphthalimidoyl Carbenes in Alkene Cyclopropanation
Reactions
por: Planas, Ferran, et al.
Publicado: (2021)