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Chiral Sugars Drive Enantioenrichment in Prebiotic Amino Acid Synthesis
[Image: see text] Chiral pentose sugars mediate the enantioselective synthesis of amino acid precursors, with the magnitude of the chiral induction dictated by a subtle cooperativity between sugar hydroxyl groups. Ribose and lyxose give opposite chiral preferences, and theoretical calculations revea...
Autores principales: | Wagner, Alexander J., Zubarev, Dmitry Yu., Aspuru-Guzik, Alán, Blackmond, Donna G. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5408343/ https://www.ncbi.nlm.nih.gov/pubmed/28470050 http://dx.doi.org/10.1021/acscentsci.7b00085 |
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