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Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory

Simultaneous adsorption modeling of four ions was predicted with a strict net charge-neutral ion-exchange theory and its corresponding equilibrium and mass balance equations. An important key to the success of this approach was the proper collection of all the data, particularly the proton adsorptio...

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Autores principales: Schulthess, Cristian P., Ndu, Udonna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5412999/
https://www.ncbi.nlm.nih.gov/pubmed/28464020
http://dx.doi.org/10.1371/journal.pone.0176743
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author Schulthess, Cristian P.
Ndu, Udonna
author_facet Schulthess, Cristian P.
Ndu, Udonna
author_sort Schulthess, Cristian P.
collection PubMed
description Simultaneous adsorption modeling of four ions was predicted with a strict net charge-neutral ion-exchange theory and its corresponding equilibrium and mass balance equations. An important key to the success of this approach was the proper collection of all the data, particularly the proton adsorption data, and the inclusion of variable concentrations of conjugate ions from the experimental pH adjustments. Using IExFit software, the ion-exchange model used here predicted the competitive retention of several ions on goethite by assuming that the co-adsorption or desorption of all ions occurred in the correct stoichiometries needed to maintain electroneutrality. This approach also revealed that the retention strength of Cl(−) ions on goethite increases in the presence of phthalate ions. That is, an anion-anion enhancement effect was observed. The retention of Cl(−) ions was much weaker than phthalate ions, and this also resulted in a higher sensitivity of the Cl(−) ions toward minor variations in the surface reactivity. The proposed model uses four goethite surface sites. The drop in retention of phthalate ions at low pH was fully described here as resulting from competitive Cl(−) reactions, which were introduced in increasing concentrations into the matrix as the conjugate base to the acid added to lower the pH.
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spelling pubmed-54129992017-05-14 Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory Schulthess, Cristian P. Ndu, Udonna PLoS One Research Article Simultaneous adsorption modeling of four ions was predicted with a strict net charge-neutral ion-exchange theory and its corresponding equilibrium and mass balance equations. An important key to the success of this approach was the proper collection of all the data, particularly the proton adsorption data, and the inclusion of variable concentrations of conjugate ions from the experimental pH adjustments. Using IExFit software, the ion-exchange model used here predicted the competitive retention of several ions on goethite by assuming that the co-adsorption or desorption of all ions occurred in the correct stoichiometries needed to maintain electroneutrality. This approach also revealed that the retention strength of Cl(−) ions on goethite increases in the presence of phthalate ions. That is, an anion-anion enhancement effect was observed. The retention of Cl(−) ions was much weaker than phthalate ions, and this also resulted in a higher sensitivity of the Cl(−) ions toward minor variations in the surface reactivity. The proposed model uses four goethite surface sites. The drop in retention of phthalate ions at low pH was fully described here as resulting from competitive Cl(−) reactions, which were introduced in increasing concentrations into the matrix as the conjugate base to the acid added to lower the pH. Public Library of Science 2017-05-02 /pmc/articles/PMC5412999/ /pubmed/28464020 http://dx.doi.org/10.1371/journal.pone.0176743 Text en © 2017 Schulthess, Ndu http://creativecommons.org/licenses/by/4.0/ This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
spellingShingle Research Article
Schulthess, Cristian P.
Ndu, Udonna
Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
title Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
title_full Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
title_fullStr Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
title_full_unstemmed Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
title_short Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
title_sort modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5412999/
https://www.ncbi.nlm.nih.gov/pubmed/28464020
http://dx.doi.org/10.1371/journal.pone.0176743
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