Using Functionalized Silyl Ligands To Suppress Solvent Coordination to Silyl Lanthanide(II) Complexes

[Image: see text] The reaction of the potassium 1,3-trisilanediide Me(2)Si[Si(Me(3)Si)(2)K](2) with SmI(2) and YbI(2) was found to give the respective disilylated complexes Me(2)Si[Si(Me(3)Si)(2)](2)Sm·2THF and Me(2)Si[Si(Me(3)Si)(2)](2)Yb·2THF. Desolvation of coordinated solvent molecules in these...

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Detalles Bibliográficos
Autores principales: Zitz, Rainer, Hlina, Johann, Aghazadeh Meshgi, Mohammad, Krenn, Heinz, Marschner, Christoph, Szilvási, Tibor, Baumgartner, Judith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5415877/
https://www.ncbi.nlm.nih.gov/pubmed/28398724
http://dx.doi.org/10.1021/acs.inorgchem.7b00420

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5415877/
https://www.ncbi.nlm.nih.gov/pubmed/28398724
http://dx.doi.org/10.1021/acs.inorgchem.7b00420

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