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Using Functionalized Silyl Ligands To Suppress Solvent Coordination to Silyl Lanthanide(II) Complexes
[Image: see text] The reaction of the potassium 1,3-trisilanediide Me(2)Si[Si(Me(3)Si)(2)K](2) with SmI(2) and YbI(2) was found to give the respective disilylated complexes Me(2)Si[Si(Me(3)Si)(2)](2)Sm·2THF and Me(2)Si[Si(Me(3)Si)(2)](2)Yb·2THF. Desolvation of coordinated solvent molecules in these...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5415877/ https://www.ncbi.nlm.nih.gov/pubmed/28398724 http://dx.doi.org/10.1021/acs.inorgchem.7b00420 |