Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine

The title compound, C(11)H(12)N(2), is not planar due to the folding of the seven-membered ring. In the crystal, mol­ecules are packed opposite each other to minimize the electronic repulsion but the long inter­molecular distances indicate that no directional contacts are found.

Detalles Bibliográficos
Autores principales: Nieto, Carla I., Claramunt, Rosa M., Torralba, M. Carmen, Torres, M. Rosario, Elguero, Jose
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418775/
https://www.ncbi.nlm.nih.gov/pubmed/28529767
http://dx.doi.org/10.1107/S2056989017004972
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author Nieto, Carla I.
Claramunt, Rosa M.
Torralba, M. Carmen
Torres, M. Rosario
Elguero, Jose
author_facet Nieto, Carla I.
Claramunt, Rosa M.
Torralba, M. Carmen
Torres, M. Rosario
Elguero, Jose
author_sort Nieto, Carla I.
collection PubMed
description The title compound, C(11)H(12)N(2), is not planar due to the folding of the seven-membered ring. In the crystal, mol­ecules are packed opposite each other to minimize the electronic repulsion but the long inter­molecular distances indicate that no directional contacts are found.
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spelling pubmed-54187752017-05-19 Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine Nieto, Carla I. Claramunt, Rosa M. Torralba, M. Carmen Torres, M. Rosario Elguero, Jose Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(11)H(12)N(2), is not planar due to the folding of the seven-membered ring. In the crystal, mol­ecules are packed opposite each other to minimize the electronic repulsion but the long inter­molecular distances indicate that no directional contacts are found. International Union of Crystallography 2017-04-04 /pmc/articles/PMC5418775/ /pubmed/28529767 http://dx.doi.org/10.1107/S2056989017004972 Text en © Nieto et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Nieto, Carla I.
Claramunt, Rosa M.
Torralba, M. Carmen
Torres, M. Rosario
Elguero, Jose
Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine
title Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine
title_full Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine
title_fullStr Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine
title_full_unstemmed Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine
title_short Crystal structure of (1Z,4Z)-2,4-dimethyl-3H-benzo[b][1,4]diazepine
title_sort crystal structure of (1z,4z)-2,4-dimethyl-3h-benzo[b][1,4]diazepine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418775/
https://www.ncbi.nlm.nih.gov/pubmed/28529767
http://dx.doi.org/10.1107/S2056989017004972
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