Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea

In the title compound, 2C(5)H(12)N(+)·SO(4) (2−)·2C(3)H(8)N(2)S, the C=S groups of the two independent 1,3-di­methyl­urea mol­ecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis­(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bon...

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Detalles Bibliográficos
Autores principales: Döring, Cindy, Lueck, Julian F. D., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418776/
https://www.ncbi.nlm.nih.gov/pubmed/28529768
http://dx.doi.org/10.1107/S2056989017004820
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author Döring, Cindy
Lueck, Julian F. D.
Jones, Peter G.
author_facet Döring, Cindy
Lueck, Julian F. D.
Jones, Peter G.
author_sort Döring, Cindy
collection PubMed
description In the title compound, 2C(5)H(12)N(+)·SO(4) (2−)·2C(3)H(8)N(2)S, the C=S groups of the two independent 1,3-di­methyl­urea mol­ecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis­(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bonded to the sulfate by N—H⋯O and C—H⋯O inter­actions. The 1,3-di­methyl­urea mol­ecules are also hydrogen bonded to sulfate O atoms, and project outwards from the ribbon parallel to the b axis.
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spelling pubmed-54187762017-05-19 Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea Döring, Cindy Lueck, Julian F. D. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, 2C(5)H(12)N(+)·SO(4) (2−)·2C(3)H(8)N(2)S, the C=S groups of the two independent 1,3-di­methyl­urea mol­ecules and the sulfur atom of the anion lie on twofold axes. The packing is centred on bis­(piperidinium) sulfate ribbons parallel to the c axis; the cations are hydrogen bonded to the sulfate by N—H⋯O and C—H⋯O inter­actions. The 1,3-di­methyl­urea mol­ecules are also hydrogen bonded to sulfate O atoms, and project outwards from the ribbon parallel to the b axis. International Union of Crystallography 2017-04-04 /pmc/articles/PMC5418776/ /pubmed/28529768 http://dx.doi.org/10.1107/S2056989017004820 Text en © Döring et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Döring, Cindy
Lueck, Julian F. D.
Jones, Peter G.
Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
title Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
title_full Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
title_fullStr Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
title_full_unstemmed Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
title_short Crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
title_sort crystal structure of the 1:2 adduct of bis­(piperidinium) sulfate and 1,3-di­methyl­thio­urea
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418776/
https://www.ncbi.nlm.nih.gov/pubmed/28529768
http://dx.doi.org/10.1107/S2056989017004820
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