Cargando…
Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate
The closely related title compounds, 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate, C(18)H(26)O(4) (I), and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate, C(16)H(20)O(4) (II), are monomers suitable for the preparation of redox polymers. They consist of a pr...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418778/ https://www.ncbi.nlm.nih.gov/pubmed/28529770 http://dx.doi.org/10.1107/S2056989017004959 |
| _version_ | 1783234112230785024 |
|---|---|
| author | Goswami, Shailesh K. Hanton, Lyall R. McAdam, C. John Moratti, Stephen C. Simpson, Jim |
| author_facet | Goswami, Shailesh K. Hanton, Lyall R. McAdam, C. John Moratti, Stephen C. Simpson, Jim |
| author_sort | Goswami, Shailesh K. |
| collection | PubMed |
| description | The closely related title compounds, 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate, C(18)H(26)O(4) (I), and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate, C(16)H(20)O(4) (II), are monomers suitable for the preparation of redox polymers. They consist of a propylmethacrylate group and three methyl substituents on dimethoxybenzene and quinone cores, respectively. Both crystal structures feature weak C—H⋯O hydrogen bonds and C—H⋯π(ring) contacts between methyl groups and the six-membered rings. |
| format | Online Article Text |
| id | pubmed-5418778 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-54187782017-05-19 Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate Goswami, Shailesh K. Hanton, Lyall R. McAdam, C. John Moratti, Stephen C. Simpson, Jim Acta Crystallogr E Crystallogr Commun Research Communications The closely related title compounds, 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate, C(18)H(26)O(4) (I), and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate, C(16)H(20)O(4) (II), are monomers suitable for the preparation of redox polymers. They consist of a propylmethacrylate group and three methyl substituents on dimethoxybenzene and quinone cores, respectively. Both crystal structures feature weak C—H⋯O hydrogen bonds and C—H⋯π(ring) contacts between methyl groups and the six-membered rings. International Union of Crystallography 2017-04-04 /pmc/articles/PMC5418778/ /pubmed/28529770 http://dx.doi.org/10.1107/S2056989017004959 Text en © Goswami et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Goswami, Shailesh K. Hanton, Lyall R. McAdam, C. John Moratti, Stephen C. Simpson, Jim Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| title | Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| title_full | Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| title_fullStr | Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| title_full_unstemmed | Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| title_short | Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| title_sort | crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418778/ https://www.ncbi.nlm.nih.gov/pubmed/28529770 http://dx.doi.org/10.1107/S2056989017004959 |
| work_keys_str_mv | AT goswamishaileshk crystalstructuresofthepolymerprecursors325dimethoxy346trimethylphenylpropylmethacrylateand3245trimethyl36dioxocyclohexa14dienylpropylmethacrylate AT hantonlyallr crystalstructuresofthepolymerprecursors325dimethoxy346trimethylphenylpropylmethacrylateand3245trimethyl36dioxocyclohexa14dienylpropylmethacrylate AT mcadamcjohn crystalstructuresofthepolymerprecursors325dimethoxy346trimethylphenylpropylmethacrylateand3245trimethyl36dioxocyclohexa14dienylpropylmethacrylate AT morattistephenc crystalstructuresofthepolymerprecursors325dimethoxy346trimethylphenylpropylmethacrylateand3245trimethyl36dioxocyclohexa14dienylpropylmethacrylate AT simpsonjim crystalstructuresofthepolymerprecursors325dimethoxy346trimethylphenylpropylmethacrylateand3245trimethyl36dioxocyclohexa14dienylpropylmethacrylate |