trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis

The Sn(IV) atom in the title diorganotin compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(2)H(6)OS)(2)], is located on a centre of inversion, resulting in the C(2)Cl(2)O(2) donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa­hedron. The crystal features C—H⋯F, C...

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Autores principales: Amin, Nur Adibah Binti Mohd, Hussen, Rusnah Syahila Duali, Lee, See Mun, Halcovitch, Nathan R., Jotani, Mukesh M., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418780/
https://www.ncbi.nlm.nih.gov/pubmed/28529772
http://dx.doi.org/10.1107/S2056989017005072
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author Amin, Nur Adibah Binti Mohd
Hussen, Rusnah Syahila Duali
Lee, See Mun
Halcovitch, Nathan R.
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_facet Amin, Nur Adibah Binti Mohd
Hussen, Rusnah Syahila Duali
Lee, See Mun
Halcovitch, Nathan R.
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_sort Amin, Nur Adibah Binti Mohd
collection PubMed
description The Sn(IV) atom in the title diorganotin compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(2)H(6)OS)(2)], is located on a centre of inversion, resulting in the C(2)Cl(2)O(2) donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa­hedron. The crystal features C—H⋯F, C—H⋯Cl and C—H⋯π inter­actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol­ecular packing are clearly evident from the analysis of the Hirshfeld surface.
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spelling pubmed-54187802017-05-19 trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis Amin, Nur Adibah Binti Mohd Hussen, Rusnah Syahila Duali Lee, See Mun Halcovitch, Nathan R. Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The Sn(IV) atom in the title diorganotin compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(2)H(6)OS)(2)], is located on a centre of inversion, resulting in the C(2)Cl(2)O(2) donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa­hedron. The crystal features C—H⋯F, C—H⋯Cl and C—H⋯π inter­actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol­ecular packing are clearly evident from the analysis of the Hirshfeld surface. International Union of Crystallography 2017-04-07 /pmc/articles/PMC5418780/ /pubmed/28529772 http://dx.doi.org/10.1107/S2056989017005072 Text en © Amin et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Amin, Nur Adibah Binti Mohd
Hussen, Rusnah Syahila Duali
Lee, See Mun
Halcovitch, Nathan R.
Jotani, Mukesh M.
Tiekink, Edward R. T.
trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis
title trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis
title_full trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis
title_fullStr trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis
title_full_unstemmed trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis
title_short trans-Di­chlorido­bis­(dimethyl sulfoxide-κO)bis­(4-fluoro­benzyl-κC (1))tin(IV): crystal structure and Hirshfeld surface analysis
title_sort trans-di­chlorido­bis­(dimethyl sulfoxide-κo)bis­(4-fluoro­benzyl-κc (1))tin(iv): crystal structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418780/
https://www.ncbi.nlm.nih.gov/pubmed/28529772
http://dx.doi.org/10.1107/S2056989017005072
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