Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide

In the mol­ecule of the title compound, C(15)H(18)N(2)OS(2), the central S(2)C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C—CN groups are trans to each other across their common C—C bond. In the crystal, one classical and two ‘weak’ hydrogen bonds combine with borderline N⋯N a...

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Autores principales: Azzam, Rasha A., Elgemeie, Galal H., Ramadan, Rokia, Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418798/
https://www.ncbi.nlm.nih.gov/pubmed/28529790
http://dx.doi.org/10.1107/S2056989017005783
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author Azzam, Rasha A.
Elgemeie, Galal H.
Ramadan, Rokia
Jones, Peter G.
author_facet Azzam, Rasha A.
Elgemeie, Galal H.
Ramadan, Rokia
Jones, Peter G.
author_sort Azzam, Rasha A.
collection PubMed
description In the mol­ecule of the title compound, C(15)H(18)N(2)OS(2), the central S(2)C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C—CN groups are trans to each other across their common C—C bond. In the crystal, one classical and two ‘weak’ hydrogen bonds combine with borderline N⋯N and S⋯S contacts to form layers parallel to (10-2). One ethyl group is disordered over two positions with relative occupancy 0.721/0.279 (7).
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spelling pubmed-54187982017-05-19 Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide Azzam, Rasha A. Elgemeie, Galal H. Ramadan, Rokia Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the mol­ecule of the title compound, C(15)H(18)N(2)OS(2), the central S(2)C=C(CN)C moiety is planar (r.m.s. deviation = 0.029 Å). The C=O and C—CN groups are trans to each other across their common C—C bond. In the crystal, one classical and two ‘weak’ hydrogen bonds combine with borderline N⋯N and S⋯S contacts to form layers parallel to (10-2). One ethyl group is disordered over two positions with relative occupancy 0.721/0.279 (7). International Union of Crystallography 2017-04-28 /pmc/articles/PMC5418798/ /pubmed/28529790 http://dx.doi.org/10.1107/S2056989017005783 Text en © Azzam et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Azzam, Rasha A.
Elgemeie, Galal H.
Ramadan, Rokia
Jones, Peter G.
Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide
title Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide
title_full Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide
title_fullStr Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide
title_full_unstemmed Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide
title_short Crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-N-o-tolyl­acryl­amide
title_sort crystal structure of 2-cyano-3,3-bis­(ethyl­sulfan­yl)-n-o-tolyl­acryl­amide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418798/
https://www.ncbi.nlm.nih.gov/pubmed/28529790
http://dx.doi.org/10.1107/S2056989017005783
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