Cargando…
Crystal structure of a new spiro-polytetrahydrofuran compound with translational pseudosymmetry: rac-(2S,2′S,5′R)-2-methyl-5′-[(1R,2R,5S,5′R)-1,4,4,5′-tetramethyldihydro-3′H-3,8-dioxaspiro[bicyclo[3.2.1]octane-2,2′-furan]-5′-yl]hexahydro[2,2′-bifuran]-5(2H)-one
The title compound, C(22)H(34)O(6), is a product of oxidation of squalene with the catalytic system RuO(4)(cat.)/NaIO(4). The asymmetric unit contains two crystallographically independent molecules of very similar geometry approximately related by the non-crystallographic translation vector c/2. As...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418806/ https://www.ncbi.nlm.nih.gov/pubmed/28529798 http://dx.doi.org/10.1107/S2056989017006065 |