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Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate
The title compound, C(10)H(8)N(2)O(2)·H(2)O, consists of an N-hydroxyquinoline-2-carboxamide molecule in the keto tautomeric form and a water molecule connected through an O—H⋯O hydrogen bond. The N-hydroxyquinoline-2-carboxamide molecule has a nearly planar structure [maximum deviation = 0.0...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418809/ https://www.ncbi.nlm.nih.gov/pubmed/28529801 http://dx.doi.org/10.1107/S2056989017005618 |
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author | Safyanova, Inna S. Ohui, Kateryna A. Omelchenko, Iryna V. Shyshkina, Svitlana V. |
author_facet | Safyanova, Inna S. Ohui, Kateryna A. Omelchenko, Iryna V. Shyshkina, Svitlana V. |
author_sort | Safyanova, Inna S. |
collection | PubMed |
description | The title compound, C(10)H(8)N(2)O(2)·H(2)O, consists of an N-hydroxyquinoline-2-carboxamide molecule in the keto tautomeric form and a water molecule connected through an O—H⋯O hydrogen bond. The N-hydroxyquinoline-2-carboxamide molecule has a nearly planar structure [maximum deviation = 0.062 (1) Å] and only the hydroxy H atom deviates significantly from the molecule plane. In the crystal, π–π stacking between the aromatic rings [intercentroid distance = 3.887 (1) Å] and intermolecular O—H⋯O hydrogen bonds organize the crystal components into columns extending along the b-axis direction. |
format | Online Article Text |
id | pubmed-5418809 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-54188092017-05-19 Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate Safyanova, Inna S. Ohui, Kateryna A. Omelchenko, Iryna V. Shyshkina, Svitlana V. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(10)H(8)N(2)O(2)·H(2)O, consists of an N-hydroxyquinoline-2-carboxamide molecule in the keto tautomeric form and a water molecule connected through an O—H⋯O hydrogen bond. The N-hydroxyquinoline-2-carboxamide molecule has a nearly planar structure [maximum deviation = 0.062 (1) Å] and only the hydroxy H atom deviates significantly from the molecule plane. In the crystal, π–π stacking between the aromatic rings [intercentroid distance = 3.887 (1) Å] and intermolecular O—H⋯O hydrogen bonds organize the crystal components into columns extending along the b-axis direction. International Union of Crystallography 2017-04-28 /pmc/articles/PMC5418809/ /pubmed/28529801 http://dx.doi.org/10.1107/S2056989017005618 Text en © Safyanova et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Safyanova, Inna S. Ohui, Kateryna A. Omelchenko, Iryna V. Shyshkina, Svitlana V. Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate |
title | Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate |
title_full | Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate |
title_fullStr | Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate |
title_full_unstemmed | Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate |
title_short | Crystal structure of N-hydroxyquinoline-2-carboxamide monohydrate |
title_sort | crystal structure of n-hydroxyquinoline-2-carboxamide monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418809/ https://www.ncbi.nlm.nih.gov/pubmed/28529801 http://dx.doi.org/10.1107/S2056989017005618 |
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