Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands

The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that...

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Detalles Bibliográficos
Autores principales: Berezhnytska, Oleksandra, Savchenko, Irina, Ivakha, Nadiya, Trunova, Olena, Rusakova, Nataliya, Smola, Sergiy, Rogovtsov, Oleksandr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5422218/
https://www.ncbi.nlm.nih.gov/pubmed/28486795
http://dx.doi.org/10.1186/s11671-017-2074-0
Descripción
Sumario:The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed.

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