Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands

The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that...

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Autores principales: Berezhnytska, Oleksandra, Savchenko, Irina, Ivakha, Nadiya, Trunova, Olena, Rusakova, Nataliya, Smola, Sergiy, Rogovtsov, Oleksandr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5422218/
https://www.ncbi.nlm.nih.gov/pubmed/28486795
http://dx.doi.org/10.1186/s11671-017-2074-0
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author Berezhnytska, Oleksandra
Savchenko, Irina
Ivakha, Nadiya
Trunova, Olena
Rusakova, Nataliya
Smola, Sergiy
Rogovtsov, Oleksandr
author_facet Berezhnytska, Oleksandra
Savchenko, Irina
Ivakha, Nadiya
Trunova, Olena
Rusakova, Nataliya
Smola, Sergiy
Rogovtsov, Oleksandr
author_sort Berezhnytska, Oleksandra
collection PubMed
description The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed.
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spelling pubmed-54222182017-05-24 Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands Berezhnytska, Oleksandra Savchenko, Irina Ivakha, Nadiya Trunova, Olena Rusakova, Nataliya Smola, Sergiy Rogovtsov, Oleksandr Nanoscale Res Lett Nano Express The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed. Springer US 2017-05-08 /pmc/articles/PMC5422218/ /pubmed/28486795 http://dx.doi.org/10.1186/s11671-017-2074-0 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Berezhnytska, Oleksandra
Savchenko, Irina
Ivakha, Nadiya
Trunova, Olena
Rusakova, Nataliya
Smola, Sergiy
Rogovtsov, Oleksandr
Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
title Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
title_full Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
title_fullStr Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
title_full_unstemmed Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
title_short Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
title_sort synthesis, characterization, and luminescent properties of polymer complexes of nd(iii) with β-dicarbonyl ligands
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5422218/
https://www.ncbi.nlm.nih.gov/pubmed/28486795
http://dx.doi.org/10.1186/s11671-017-2074-0
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