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Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)

Wide bandgap perovskite oxides with high room temperature conductivities and structural compatibility with a diverse family of organic/inorganic perovskite materials are of significant interest as transparent conductors and as active components in power electronics. Such materials must also possess...

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Autores principales: Prakash, Abhinav, Xu, Peng, Faghaninia, Alireza, Shukla, Sudhanshu, Ager, Joel W., Lo, Cynthia S., Jalan, Bharat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424175/
https://www.ncbi.nlm.nih.gov/pubmed/28474675
http://dx.doi.org/10.1038/ncomms15167
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author Prakash, Abhinav
Xu, Peng
Faghaninia, Alireza
Shukla, Sudhanshu
Ager, Joel W.
Lo, Cynthia S.
Jalan, Bharat
author_facet Prakash, Abhinav
Xu, Peng
Faghaninia, Alireza
Shukla, Sudhanshu
Ager, Joel W.
Lo, Cynthia S.
Jalan, Bharat
author_sort Prakash, Abhinav
collection PubMed
description Wide bandgap perovskite oxides with high room temperature conductivities and structural compatibility with a diverse family of organic/inorganic perovskite materials are of significant interest as transparent conductors and as active components in power electronics. Such materials must also possess high room temperature mobility to minimize power consumption and to enable high-frequency applications. Here, we report n-type BaSnO(3) films grown using hybrid molecular beam epitaxy with room temperature conductivity exceeding 10(4) S cm(−1). Significantly, these films show room temperature mobilities up to 120 cm(2) V(−1) s(−1) even at carrier concentrations above 3 × 10(20) cm(−3) together with a wide bandgap (3 eV). We examine the mobility-limiting scattering mechanisms by calculating temperature-dependent mobility, and Seebeck coefficient using the Boltzmann transport framework and ab-initio calculations. These results place perovskite oxide semiconductors for the first time on par with the highly successful III–N system, thereby bringing all-transparent, high-power oxide electronics operating at room temperature a step closer to reality.
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spelling pubmed-54241752017-05-23 Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1) Prakash, Abhinav Xu, Peng Faghaninia, Alireza Shukla, Sudhanshu Ager, Joel W. Lo, Cynthia S. Jalan, Bharat Nat Commun Article Wide bandgap perovskite oxides with high room temperature conductivities and structural compatibility with a diverse family of organic/inorganic perovskite materials are of significant interest as transparent conductors and as active components in power electronics. Such materials must also possess high room temperature mobility to minimize power consumption and to enable high-frequency applications. Here, we report n-type BaSnO(3) films grown using hybrid molecular beam epitaxy with room temperature conductivity exceeding 10(4) S cm(−1). Significantly, these films show room temperature mobilities up to 120 cm(2) V(−1) s(−1) even at carrier concentrations above 3 × 10(20) cm(−3) together with a wide bandgap (3 eV). We examine the mobility-limiting scattering mechanisms by calculating temperature-dependent mobility, and Seebeck coefficient using the Boltzmann transport framework and ab-initio calculations. These results place perovskite oxide semiconductors for the first time on par with the highly successful III–N system, thereby bringing all-transparent, high-power oxide electronics operating at room temperature a step closer to reality. Nature Publishing Group 2017-05-05 /pmc/articles/PMC5424175/ /pubmed/28474675 http://dx.doi.org/10.1038/ncomms15167 Text en Copyright © 2017, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Prakash, Abhinav
Xu, Peng
Faghaninia, Alireza
Shukla, Sudhanshu
Ager, Joel W.
Lo, Cynthia S.
Jalan, Bharat
Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)
title Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)
title_full Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)
title_fullStr Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)
title_full_unstemmed Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)
title_short Wide bandgap BaSnO(3) films with room temperature conductivity exceeding 10(4) S cm(−1)
title_sort wide bandgap basno(3) films with room temperature conductivity exceeding 10(4) s cm(−1)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424175/
https://www.ncbi.nlm.nih.gov/pubmed/28474675
http://dx.doi.org/10.1038/ncomms15167
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