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Nature's hydrides: rapid reduction of halocarbons by folate model compounds

Halocarbons R–X are reduced to hydrocarbons R–H by folate model compounds under biomimetic conditions. The reactions correspond to a halide–hydride exchange with the methylenetetrahydrofolate (MTHF) models acting as hydride donors. The MTHF models are also functional equivalents of dehalohydrogenase...

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Detalles Bibliográficos
Autores principales:	Denk, Michael K., Milutinović, Nicholas S., Marczenko, Katherine M., Sadowski, Natalie M., Paschos, Athanasios
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424806/ https://www.ncbi.nlm.nih.gov/pubmed/28553478 http://dx.doi.org/10.1039/c6sc04314c

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