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The influence of acceptor nucleophilicity on the glycosylation reaction mechanism
A set of model nucleophiles of gradually changing nucleophilicity is used to probe the glycosylation reaction mechanism. Glycosylations of ethanol-based acceptors, bearing varying amounts of fluorine atoms, report on the dependency of the stereochemistry in condensation reactions on the nucleophilic...
Autores principales: | van der Vorm, S., Hansen, T., Overkleeft, H. S., van der Marel, G. A., Codée, J. D. C. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5424809/ https://www.ncbi.nlm.nih.gov/pubmed/28553477 http://dx.doi.org/10.1039/c6sc04638j |
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