Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts

The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH(3))(4)Cl(2)](+) of quasi-octahedral symmetry...

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Autores principales: Kochetova, Svetlana, Savchuk, Anastasiya, Shakhnin, Dmytro, Malyshev, Viktor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5425359/
https://www.ncbi.nlm.nih.gov/pubmed/28499333
http://dx.doi.org/10.1186/s11671-017-2108-7
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author Kochetova, Svetlana
Savchuk, Anastasiya
Shakhnin, Dmytro
Malyshev, Viktor
author_facet Kochetova, Svetlana
Savchuk, Anastasiya
Shakhnin, Dmytro
Malyshev, Viktor
author_sort Kochetova, Svetlana
collection PubMed
description The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH(3))(4)Cl(2)](+) of quasi-octahedral symmetry D(4h) are produced. The composition and structure of nascent complex ions have been studied. During electrochemical reduction of [Rh(NH(3))(4)Cl(2)](+) complexes, the synthesis of Rh nanoparticles, as well as Fe, Cu, and Mo nanocoatings, were realized.
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spelling pubmed-54253592017-05-24 Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts Kochetova, Svetlana Savchuk, Anastasiya Shakhnin, Dmytro Malyshev, Viktor Nanoscale Res Lett Nano Express The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH(3))(4)Cl(2)](+) of quasi-octahedral symmetry D(4h) are produced. The composition and structure of nascent complex ions have been studied. During electrochemical reduction of [Rh(NH(3))(4)Cl(2)](+) complexes, the synthesis of Rh nanoparticles, as well as Fe, Cu, and Mo nanocoatings, were realized. Springer US 2017-05-11 /pmc/articles/PMC5425359/ /pubmed/28499333 http://dx.doi.org/10.1186/s11671-017-2108-7 Text en © The Author(s). 2017 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Kochetova, Svetlana
Savchuk, Anastasiya
Shakhnin, Dmytro
Malyshev, Viktor
Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
title Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
title_full Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
title_fullStr Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
title_full_unstemmed Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
title_short Electrochemical Behavior and Electrodeposition of Nanostructured Rhodium from Low-Temperature Carbamide and Acetamide Containing Melts
title_sort electrochemical behavior and electrodeposition of nanostructured rhodium from low-temperature carbamide and acetamide containing melts
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5425359/
https://www.ncbi.nlm.nih.gov/pubmed/28499333
http://dx.doi.org/10.1186/s11671-017-2108-7
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AT shakhnindmytro electrochemicalbehaviorandelectrodepositionofnanostructuredrhodiumfromlowtemperaturecarbamideandacetamidecontainingmelts
AT malyshevviktor electrochemicalbehaviorandelectrodepositionofnanostructuredrhodiumfromlowtemperaturecarbamideandacetamidecontainingmelts

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