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High temperature ferromagnetism in π-conjugated two-dimensional metal–organic frameworks
We use first-principles calculations to show that the square symmetry of two-dimensional (2D) metal–organic frameworks (MOFs) made from octaamino-substituted phthalocyanines and square planar Ni(2+) ions, which enable strong conjugation of π electrons, has a critical impact on the magnetic propertie...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5428024/ https://www.ncbi.nlm.nih.gov/pubmed/28553524 http://dx.doi.org/10.1039/c6sc05080h |