Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework

A titanium-based zeolitic thiophene-benzimidazolate framework has been designed for the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide. The developed catalyst activates carbon dioxide and delivers over 16% yield of DMC without the use of any dehydrating agent or requir...

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Autores principales: Verma, Sanny, Baig, R. B. Nasir, Nadagouda, Mallikarjuna N., Varma, Rajender S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5429631/
https://www.ncbi.nlm.nih.gov/pubmed/28381827
http://dx.doi.org/10.1038/s41598-017-00736-1
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author Verma, Sanny
Baig, R. B. Nasir
Nadagouda, Mallikarjuna N.
Varma, Rajender S.
author_facet Verma, Sanny
Baig, R. B. Nasir
Nadagouda, Mallikarjuna N.
Varma, Rajender S.
author_sort Verma, Sanny
collection PubMed
description A titanium-based zeolitic thiophene-benzimidazolate framework has been designed for the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide. The developed catalyst activates carbon dioxide and delivers over 16% yield of DMC without the use of any dehydrating agent or requirement for azeotropic distillation.
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spelling pubmed-54296312017-05-15 Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework Verma, Sanny Baig, R. B. Nasir Nadagouda, Mallikarjuna N. Varma, Rajender S. Sci Rep Article A titanium-based zeolitic thiophene-benzimidazolate framework has been designed for the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide. The developed catalyst activates carbon dioxide and delivers over 16% yield of DMC without the use of any dehydrating agent or requirement for azeotropic distillation. Nature Publishing Group UK 2017-04-05 /pmc/articles/PMC5429631/ /pubmed/28381827 http://dx.doi.org/10.1038/s41598-017-00736-1 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Verma, Sanny
Baig, R. B. Nasir
Nadagouda, Mallikarjuna N.
Varma, Rajender S.
Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
title Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
title_full Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
title_fullStr Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
title_full_unstemmed Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
title_short Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
title_sort fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5429631/
https://www.ncbi.nlm.nih.gov/pubmed/28381827
http://dx.doi.org/10.1038/s41598-017-00736-1
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