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A high-power and fast charging Li-ion battery with outstanding cycle-life

Electrochemical energy storage devices based on Li-ion cells currently power almost all electronic devices and power tools. The development of new Li-ion cell configurations by incorporating innovative functional components (electrode materials and electrolyte formulations) will allow to bring this...

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Detalles Bibliográficos
Autores principales: Agostini, M., Brutti, S., Navarra, M. A., Panero, S., Reale, P., Matic, A., Scrosati, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5430621/
https://www.ncbi.nlm.nih.gov/pubmed/28439085
http://dx.doi.org/10.1038/s41598-017-01236-y
Descripción
Sumario:Electrochemical energy storage devices based on Li-ion cells currently power almost all electronic devices and power tools. The development of new Li-ion cell configurations by incorporating innovative functional components (electrode materials and electrolyte formulations) will allow to bring this technology beyond mobile electronics and to boost performance largely beyond the state-of-the-art. Here we demonstrate a new full Li-ion cell constituted by a high-potential cathode material, i.e. LiNi(0.5)Mn(1.5)O(4), a safe nanostructured anode material, i.e. TiO(2), and a composite electrolyte made by a mixture of an ionic liquid suitable for high potential applications, i.e. Pyr(1,4)PF(6), a lithium salt, i.e. LiPF(6), and standard organic carbonates. The final cell configuration is able to reversibly cycle lithium for thousands of cycles at 1000 mAg(−1) and a capacity retention of 65% at cycle 2000.