Exploring quantum Griffiths phase in Ni(1−x)V(x) nanoalloys

Metallic Ni(1−x)V(x) alloys exhibit a ferromagnetic to paramagnetic disordered quantum phase transition in bulk. Such a phase transition is accompanied by a quantum Griffiths phase (QGP), featuring fractional power-law temperature dependences of physical variables, like magnetic susceptibility and specific heat, at low temperatures. As nanoparticles (NP’s) usually exhibit properties significantly different from their bulk counterparts, it is intriguing to explore the occurrence of quantum Griffiths phase in Ni(1−x)V(x) nanoalloys. NP’s of Ni(1−x)V(x) (0 ≤ x ≤ 0.17) alloys are prepared by a chemical reflux method. The structure and composition of the nanoalloys are determined by X-ray diffraction, X-ray photoelectron spectroscopy and electron microscopy techniques. Metallicity of the samples has been ensured by electrical resistivity measurements. DC magnetization results suggest that ferromagnetism persists in the NP’s until x = 0.17. Low-temperature upturns in magnetic susceptibility and heat capacity hint at critical fluctuations evolving with V-doping. The fluctuations might stem from isolated Ni-clusters within the ferromagnetic NP, indicating a QGP region ranging from x = 0.085 to x ≫ 0.17.