Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(ii)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide product...

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Detalles Bibliográficos
Autores principales: Williamson, Patrick, Galván, Alicia, Gaunt, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5431632/
https://www.ncbi.nlm.nih.gov/pubmed/28553492
http://dx.doi.org/10.1039/c6sc05581h
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author Williamson, Patrick
Galván, Alicia
Gaunt, Matthew J.
author_facet Williamson, Patrick
Galván, Alicia
Gaunt, Matthew J.
author_sort Williamson, Patrick
collection PubMed
description A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(ii)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide products bearing diverse functional groups that can be successfully accessed via this methodology.
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spelling pubmed-54316322017-05-26 Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides Williamson, Patrick Galván, Alicia Gaunt, Matthew J. Chem Sci Chemistry A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(ii)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide products bearing diverse functional groups that can be successfully accessed via this methodology. Royal Society of Chemistry 2017-04-01 2017-01-10 /pmc/articles/PMC5431632/ /pubmed/28553492 http://dx.doi.org/10.1039/c6sc05581h Text en This journal is © The Royal Society of Chemistry 2017 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Williamson, Patrick
Galván, Alicia
Gaunt, Matthew J.
Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
title Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
title_full Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
title_fullStr Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
title_full_unstemmed Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
title_short Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides
title_sort cobalt-catalysed c–h carbonylative cyclisation of aliphatic amides
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5431632/
https://www.ncbi.nlm.nih.gov/pubmed/28553492
http://dx.doi.org/10.1039/c6sc05581h
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AT galvanalicia cobaltcatalysedchcarbonylativecyclisationofaliphaticamides
AT gauntmatthewj cobaltcatalysedchcarbonylativecyclisationofaliphaticamides

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