Cargando…

Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(ii)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide product...

Descripción completa

Detalles Bibliográficos
Autores principales:	Williamson, Patrick, Galván, Alicia, Gaunt, Matthew J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5431632/ https://www.ncbi.nlm.nih.gov/pubmed/28553492 http://dx.doi.org/10.1039/c6sc05581h

Ejemplares similares

Diastereoselective C–H carbonylative annulation of aliphatic amines: a rapid route to functionalized γ-lactams
por: Png, Zhuang Mao, et al.
Publicado: (2018)

Bi(OTf)(3)-catalysed intramolecular cyclisation of unsaturated acetals
por: Saget, Raphaël, et al.
Publicado: (2021)

s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols
por: Fairley, Michael, et al.
Publicado: (2019)

Cobalt catalysed aminocarbonylation of thiols in batch and flow for the preparation of amides
por: Orduña, Jose Maria, et al.
Publicado: (2021)

Nickel-catalysed retro-hydroamidocarbonylation of aliphatic amides to olefins
por: Hu, Jiefeng, et al.
Publicado: (2017)

Ru-catalysed oxidative cyclisation of 1,5-dienes: an unprecedented role for the co-oxidant
por: Hussein, Aqeel A.
Publicado: (2020)

Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp(3))–H bonds of aliphatic amine substrates
por: Wang, Chao, et al.
Publicado: (2015)

Ligand-assisted palladium-catalyzed C–H alkenylation of aliphatic amines for the synthesis of functionalized pyrrolidines
por: He, Chuan, et al.
Publicado: (2017)

Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines
por: Nako, Adi E., et al.
Publicado: (2016)

Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds
por: Barsu, Nagaraju, et al.
Publicado: (2017)

Nickel-catalyzed transamidation of aliphatic amide derivatives
por: Dander, Jacob E., et al.
Publicado: (2017)

Cobalt-catalysed reductive C–H alkylation of indoles using carboxylic acids and molecular hydrogen
por: Cabrero-Antonino, Jose R., et al.
Publicado: (2017)

Approaches for peptide and protein cyclisation
por: Hayes, Heather C., et al.
Publicado: (2021)

Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles
por: Kuijpers, Petrus F., et al.
Publicado: (2017)

Palladium-catalysed cyclisation of alkenols: Synthesis of oxaheterocycles as core intermediates of natural compounds
por: Palík, Miroslav, et al.
Publicado: (2014)

Palladium catalysed carbonylation of 2-iodoglycals for the synthesis of C-2 carboxylic acids and aldehydes taking formic acid as a carbonyl source
por: Ahmed, Ajaz, et al.
Publicado: (2019)

A modular route to boron doped PAHs by combining borylative cyclisation and electrophilic C–H borylation
por: Crossley, D. L., et al.
Publicado: (2017)

Mechanistic insights into boron-catalysed direct amidation reactions
por: Arkhipenko, Sergey, et al.
Publicado: (2018)

Cobalt(iii)-catalyzed site-selective C–H amidation of pyridones and isoquinolones
por: Gao, Feng, et al.
Publicado: (2018)

Cobalt-catalysed asymmetric hydrovinylation of 1,3-dienes
por: Timsina, Yam N., et al.
Publicado: (2015)

Peptide cyclisation promoted by supramolecular complex formation
por: Hartendorp, Arnout P. T., et al.
Publicado: (2021)

Sesquiterpene Cyclisations Catalysed inside the Resorcinarene Capsule and Application in the Short Synthesis of Isolongifolene and Isolongifolenone
por: Zhang, Qi, et al.
Publicado: (2018)

Asymmetric Palladium-Catalysed Intramolecular Wacker-Type Cyclisations of Unsaturated Alcohols and Amino Alcohols
por: Doháňošová, Jana, et al.
Publicado: (2013)

Zinc catalysed electrophilic C–H borylation of heteroarenes
por: Grundy, Matthew E., et al.
Publicado: (2021)

Enantioselective synthesis of d-α-amino amides from aliphatic aldehydes
por: Schwieter, Kenneth E., et al.
Publicado: (2015)

Unravelling the mechanism of cobalt-catalysed remote C–H nitration of 8-aminoquinolinamides and expansion of substrate scope towards 1-naphthylpicolinamide
por: Chu, Melody, et al.
Publicado: (2019)

Light-driven reduction of aromatic olefins in aqueous media catalysed by aminopyridine cobalt complexes
por: Casadevall, Carla, et al.
Publicado: (2022)

The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C–H bonds
por: Hogg, Kirsten F., et al.
Publicado: (2017)

DFT calculations on the mechanism of copper-catalysed tandem arylation–cyclisation reactions of alkynes and diaryliodonium salts
por: Stenczel, Tamás Károly, et al.
Publicado: (2018)

Indium‐Catalysed Transfer Hydrogenation for the Reductive Cyclisation of 2‐Alkynyl Enones towards Trisubstituted Furans
por: Li, Luomo, et al.
Publicado: (2021)

Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
por: Metsänen, Toni T., et al.
Publicado: (2015)

Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium‐Catalysed C−H Amidation
por: Antoni, Patrick W., et al.
Publicado: (2020)

Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds
por: Short, Melanie A., et al.
Publicado: (2019)

Nanolayered cobalt–molybdenum sulphides (Co–Mo–S) catalyse borrowing hydrogen C–S bond formation reactions of thiols or H(2)S with alcohols
por: Sorribes, Iván, et al.
Publicado: (2019)

Engineered myoglobin as a catalyst for atom transfer radical cyclisation
por: Lubskyy, Andriy, et al.
Publicado: (2022)

Conversion of viridicatic acid to crustosic acid by cytochrome P450 enzyme-catalysed hydroxylation and spontaneous cyclisation
por: Zhou, Jenny, et al.
Publicado: (2021)

Amide synthesis via nickel-catalysed reductive aminocarbonylation of aryl halides with nitroarenes
por: Cheung, Chi Wai, et al.
Publicado: (2017)

Synthetic and biosynthetic methods for selective cyclisations of 4,5-epoxy alcohols to tetrahydropyrans
por: Bowen, James I., et al.
Publicado: (2022)

Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
por: Komeyama, Kimihiro, et al.
Publicado: (2021)

Reversed reactivity of anilines with alkynes in the rhodium-catalysed C–H activation/carbonylation tandem
por: Midya, Siba P., et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_85aivs8skcine6oo1i9he57d0i